5,10,15-tris(pentafluorophenyl)corrole cobalt(III) triphenyl phosphine

Base Information

• Chemical Name: 5,10,15-tris(pentafluorophenyl)corrole cobalt(III) triphenyl phosphine
• CAS No.: 226922-76-5
• Molecular Formula: C₅₅H₂₃CoF₁₅N₄P
• Molecular Weight: 1114.76
• Mol file: 226922-76-5.mol

Synonyms:5,10,15-tris(pentafluorophenyl)corrole cobalt(III) triphenyl phosphine

Chemical Property of 5,10,15-tris(pentafluorophenyl)corrole cobalt(III) triphenyl phosphine

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 5,10,15-tris(pentafluorophenyl)corrole cobalt(III) triphenyl phosphine

There total 4 articles about 5,10,15-tris(pentafluorophenyl)corrole cobalt(III) triphenyl phosphine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

cobalt(II) diacetate tetrahydrate (6147-53-1) + triphenylphosphine (603-35-0) + 5,10,15-tris(2,3,4,5,6-pentafluorophenyl)corrole (238402-21-6) → 5,10,15-tris(pentafluorophenyl)corrole cobalt(III) triphenyl phosphine (226922-76-5)

Guidance literature:

5,10,15-tris(2,3,4,5,6-pentafluorophenyl)corrole; With sodium acetate; In ethanol; for 0.0833333h;

cobalt(II) diacetate tetrahydrate; triphenylphosphine; In ethanol; for 1.5h;

DOI:10.1002/ejic.201900996

Reference yield: 3.0%

5,10,15-tris(pentafluorophenyl)corrole (238402-21-6) + cobalt(II) diacetate tetrahydrate (6147-53-1) + triphenylphosphine (603-35-0) → 5,10,15-tris(pentafluorophenyl)corrole cobalt(III) triphenyl phosphine (226922-76-5) + C19H9N4(C6F5)3(SO2Cl)2

Guidance literature:

In not given; piperidine/reflux;

DOI:10.1021/ja025851g

Reference yield:

5,10,15-tris(pentafluorophenyl)corrole (238402-21-6) + cobalt(II) diacetate tetrahydrate (6147-53-1) + triphenylphosphine (603-35-0) → 5,10,15-tris(pentafluorophenyl)corrole cobalt(III) triphenyl phosphine (226922-76-5)

Guidance literature:

With NaOAc; In ethanol; react. Co(OAc)2*4H2O, NaOAc, H3tpfc, and PPh3 in EtOH;

upstream raw materials:

5,10,15-tris(pentafluorophenyl)corrole

cobalt(II) diacetate tetrahydrate

triphenylphosphine

[(5,10,15-tris(pentafluorophenyl)corrolato)cobalt(III)bis(pyridine)]

Downstream raw materials:

Co(5,10,15-tris(pentafluorophenyl)corrole)^(2-)

Co(5,10,15-tris(pentafluorophenyl)corrole)^(1-)