[1,4-bis(3,5-di-tert-butylphenyl)-2,3-dimethyl-1,4-diaza-1,3-butadiene]dimethylpalladium(II)

Base Information

• Chemical Name: [1,4-bis(3,5-di-tert-butylphenyl)-2,3-dimethyl-1,4-diaza-1,3-butadiene]dimethylpalladium(II)
• CAS No.: 609810-34-6
• Molecular Formula: C₃₄H₅₄N₂Pd
• Molecular Weight: 597.236
• Mol file: 609810-34-6.mol

Synonyms:[1,4-bis(3,5-di-tert-butylphenyl)-2,3-dimethyl-1,4-diaza-1,3-butadiene]dimethylpalladium(II)

Chemical Property of [1,4-bis(3,5-di-tert-butylphenyl)-2,3-dimethyl-1,4-diaza-1,3-butadiene]dimethylpalladium(II)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [1,4-bis(3,5-di-tert-butylphenyl)-2,3-dimethyl-1,4-diaza-1,3-butadiene]dimethylpalladium(II)

There total 1 articles about [1,4-bis(3,5-di-tert-butylphenyl)-2,3-dimethyl-1,4-diaza-1,3-butadiene]dimethylpalladium(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 63.0%

dimethyl(pyridazine)palladium(II) + 1,4-bis(3,5-di-tert-butylphenyl)-2,3-dimethyl-1,4-diaza-1,3-butadiene (404373-20-2) → [1,4-bis(3,5-di-tert-butylphenyl)-2,3-dimethyl-1,4-diaza-1,3-butadiene]dimethylpalladium(II) (609810-34-6)

Guidance literature:

In diethyl ether; Schlenk flask charged with ((pyridazine)PdMe2)n and the ligand, cooled to 0 °C, and Et2O transferred via cannula onto solids; mixt. stirred for 2 h at 0 °C and warmed to room temp.; mixt. filtered; crude product dissolved in CH2Cl2; soln. filtered through Celite and concd. in vacuo; elem. anal.;

DOI:10.1021/om0303294

Reference yield:

tetrafluoroboric acid + [1,4-bis(3,5-di-tert-butylphenyl)-2,3-dimethyl-1,4-diaza-1,3-butadiene]dimethylpalladium(II) (609810-34-6) + water (7732-18-5) + oxygen (80937-33-3) → bis[(1,4-bis(3,5-di-tert-butylphenyl)-2,3-dimethyl-1,4-diaza-1,3-butadiene)(μ-hydroxo)palladium(II)] tetrafluoroborate + palladium (7440-05-3)

Guidance literature:

With benzene or benzene-d6; D₂O; In water; byproducts: methane or CH3D, biphenyl; dry trifluoroethanol-d3 added to NMR tube contg. the Pd complex; aq. HBF4 added; mixt. shaken to form clear soln.; D2O added; tube frozen at -78°C, evacuated and filled with 1 atm of O2; after thawing, benzen e added; react. temp.: 1-40 °C; product isolated cleanly; Kinetics;

DOI:10.1021/om0303294

Reference yield:

tetrafluoroboric acid + [1,4-bis(3,5-di-tert-butylphenyl)-2,3-dimethyl-1,4-diaza-1,3-butadiene]dimethylpalladium(II) (609810-34-6) + water (7732-18-5) → aqua[1,4-bis(3,5-di-tert-butylphenyl)-2,3-dimethyl-1,4-diaza-1,3-butadiene]methylpalladium(II) tetrafluoroborate (609810-30-2)

Guidance literature:

In water; dry trifluoroethanol-d3 added to NMR tube contg. the Pd complex; aq. HBF4 added; mixt. shaken to form clear soln.; not isolated; NMR anal.;

DOI:10.1021/om0303294

upstream raw materials:

1,4-bis(3,5-di-tert-butylphenyl)-2,3-dimethyl-1,4-diaza-1,3-butadiene

Downstream raw materials:

aqua[1,4-bis(3,5-di-tert-butylphenyl)-2,3-dimethyl-1,4-diaza-1,3-butadiene]methylpalladium(II) tetrafluoroborate

palladium