(2S,3S)-2-isopropyl-2-methyl-3-[(S)-2-(p-toluenesulfinyl)phenyl]oxirane

Base Information

Chemical Name:(2S,3S)-2-isopropyl-2-methyl-3-[(S)-2-(p-toluenesulfinyl)phenyl]oxirane
CAS No.:1029690-19-4
Molecular Formula:C₁₉H₂₂O₂S
Molecular Weight:314.448
Hs Code.:

Synonyms:(2S,3S)-2-isopropyl-2-methyl-3-[(S)-2-(p-toluenesulfinyl)phenyl]oxirane

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (2S,3S)-2-isopropyl-2-methyl-3-[(S)-2-(p-toluenesulfinyl)phenyl]oxirane

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Technology Process of (2S,3S)-2-isopropyl-2-methyl-3-[(S)-2-(p-toluenesulfinyl)phenyl]oxirane

There total 1 articles about (2S,3S)-2-isopropyl-2-methyl-3-[(S)-2-(p-toluenesulfinyl)phenyl]oxirane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

: 563-80-4
3-methyl-butan-2-one

: 1029690-05-8
(S)-2-(p-toluenesulfinyl)benzyl iodide

: 1029690-19-4
(2S,3S)-2-isopropyl-2-methyl-3-[(S)-2-(p-toluenesulfinyl)phenyl]oxirane

Guidance literature:: 3-methyl-butan-2-one; (S)-2-(p-toluenesulfinyl)benzyl iodide; With sodium hexamethyldisilazane; In tetrahydrofuran; at -78 ℃; for 0.0166667h; Inert atmosphere;

With water; ammonium chloride; In tetrahydrofuran; at -78 ℃; optical yield given as %de; Inert atmosphere;
DOI:10.1021/ol8005387

Reference yield: 75.0%

: 1029690-19-4
(2S,3S)-2-isopropyl-2-methyl-3-[(S)-2-(p-toluenesulfinyl)phenyl]oxirane

: 1029690-29-6
(2S,3S)-2-isopropyl-2-methyl-3-phenyloxirane

Guidance literature:: (2S,3S)-2-isopropyl-2-methyl-3-[(S)-2-(p-toluenesulfinyl)phenyl]oxirane; With tert.-butyl lithium; In tetrahydrofuran; at -78 ℃; for 0.25h; Inert atmosphere;

With water; ammonium chloride; In tetrahydrofuran; Inert atmosphere;
DOI:10.1021/ol8005387