Ph₂Pt((2,6-Me₂C₆H₃)-N=C(Me)-C(Me)=N-(2,6-Me₂C₆H₃))

Base Information

Chemical Name:Ph₂Pt((2,6-Me₂C₆H₃)-N=C(Me)-C(Me)=N-(2,6-Me₂C₆H₃))
CAS No.:312925-30-7
Molecular Formula:C₃₂H₃₄N₂Pt
Molecular Weight:641.715
Hs Code.:

Ph<sub>2</sub>Pt((2,6-Me<sub>2</sub>C<sub>6</sub>H<sub>3</sub>)-N=C(Me)-C(Me)=N-(2,6-Me<sub>2</sub>C<sub>6</sub>H<sub>3</sub>))

Synonyms:Ph₂Pt((2,6-Me₂C₆H₃)-N=C(Me)-C(Me)=N-(2,6-Me₂C₆H₃))

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Chemical Property of Ph₂Pt((2,6-Me₂C₆H₃)-N=C(Me)-C(Me)=N-(2,6-Me₂C₆H₃))

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Technology Process of Ph₂Pt((2,6-Me₂C₆H₃)-N=C(Me)-C(Me)=N-(2,6-Me₂C₆H₃))

There total 4 articles about Ph₂Pt((2,6-Me₂C₆H₃)-N=C(Me)-C(Me)=N-(2,6-Me₂C₆H₃)) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

: Pt^IIPh₂(SMe₂)₂

: 49673-40-7
N,N'-bis(2,6-dimethylphenyl)butane-2,3-diimine

: 312925-30-7
Ph₂Pt((2,6-Me₂C₆H₃)-N=C(Me)-C(Me)=N-(2,6-Me₂C₆H₃))

Guidance literature:: In toluene; a mixt. in toluene was stirred at 45°C for 18 h; pentane was aded, the mixt. was slowly cooled to ambient temp., decanted, ppt. was washed with pentane and dried in vac.; elem. anal.;
DOI:10.1021/ja0017460

Reference yield: 78.0%

: PtCl(methyl)(dimethyl sulfide)2

: 49673-40-7
N,N'-bis(2,6-dimethylphenyl)butane-2,3-diimine

: 591-51-5
phenyllithium

: 312925-38-5
[2,6-Me₂C₆H₃N=C(Me)C(Me)=N-2,6-Me₂C₆H₃]Pt(Me)(Ph)

: 312925-30-7
Ph₂Pt((2,6-Me₂C₆H₃)-N=C(Me)-C(Me)=N-(2,6-Me₂C₆H₃))

Guidance literature:: In diethyl ether; dichloromethane; under N2; addn. of SMe2 to Pt complex, suspn. cooled to -78°C, dropwise addn. of PhLi in cyclohexane/ether, stirring overnight, excess ofLi reagent removed by addn. of tert-butyl bromide, soln. of diimine in CH2Cl2 added, warming to room temp.; evapn. under vac., residue dissolved in CH2Cl2, filtration through Celite, filtrate stirred at room temp. for 4 h, filtration through alumina, filtrate evapd., residue washed with pentane, dried under vac.;
DOI:10.1021/om050899z

Reference yield: 55.0%

: cis-(PtPh₂(SMe₂)2)

: 49673-40-7
N,N'-bis(2,6-dimethylphenyl)butane-2,3-diimine

: 312925-30-7
Ph₂Pt((2,6-Me₂C₆H₃)-N=C(Me)-C(Me)=N-(2,6-Me₂C₆H₃))

Guidance literature:: In toluene; diimine added to soln. of Pt complex in toluene; mixt. stirred for 4 h; filtered; solvent removed (vac.); residue dissolved (CH2Cl2); filtered; pentane added; powder recrystd. (CH2Cl2/pentane); elem. anal.;
DOI:10.1021/ja056694z