Oxirane, 2-(1,1-dimethylethyl)-2-trimethylsilyl-

Base Information

• Chemical Name: Oxirane, 2-(1,1-dimethylethyl)-2-trimethylsilyl-
• CAS No.: 114693-78-6
• Molecular Formula: C₉H₂₀OSi
• Molecular Weight: 172.343
• DSSTox Substance ID: DTXSID80921466
• Mol file: 114693-78-6.mol

Synonyms:114693-78-6;Oxirane, 2-(1,1-dimethylethyl)-2-trimethylsilyl-;(2-tert-butyloxiran-2-yl)-trimethylsilane;DTXSID80921466;(2-tert-Butyloxiran-2-yl)(trimethyl)silane

Chemical Property of Oxirane, 2-(1,1-dimethylethyl)-2-trimethylsilyl-

Chemical Property:

• Vapor Pressure: 2.04mmHg at 25°C
• Boiling Point: 169.5°Cat760mmHg
• Flash Point: 42.4°C
• PSA: 12.53000
• Density: 0.85g/cm³
• LogP: 3.09880
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 2
• Exact Mass: 172.128341792
• Heavy Atom Count: 11
• Complexity: 163

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC(C)(C)C1(CO1)[Si](C)(C)C

Technology Process of Oxirane, 2-(1,1-dimethylethyl)-2-trimethylsilyl-

There total 3 articles about Oxirane, 2-(1,1-dimethylethyl)-2-trimethylsilyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

(Z)-1-(trimethylsilyl)-3,3-dimethyl-1-butene (26567-95-3) → cis-(trimethylsilyl)-1,2-epoxy-3,3-dimethylbutane (114693-78-6,121919-92-4,127414-66-8)

Guidance literature:

With 3-chloro-benzenecarboperoxoic acid; In dichloromethane; at 25 ℃; for 2h;

DOI:10.1016/S0040-4039(00)76172-7

Reference yield: 56.0%

((E)-3,3-Dimethyl-but-1-enyl)-trimethyl-silane (20107-37-3) → trans-2-tert-butyl-3-(trimethylsilyl)oxirane (114693-78-6)

Guidance literature:

With disodium hydrogenphosphate; 3-chloro-benzenecarboperoxoic acid; In dichloromethane; Ambient temperature;

DOI:10.1021/jo00278a013

Reference yield:

(3,3-dimethyl-1-butynyl)trimethylsilane (14630-42-3) → cis-(trimethylsilyl)-1,2-epoxy-3,3-dimethylbutane (114693-78-6,121919-92-4,127414-66-8)

Guidance literature:

Multi-step reaction with 2 steps

1: DIBAL-H / diethyl ether / 4 h / Heating

2: 63 percent / 85percent m-chloroperbenzoic acid, Na₂HPO₄ / CH₂Cl₂ / Ambient temperature

With disodium hydrogenphosphate; diisobutylaluminium hydride; 3-chloro-benzenecarboperoxoic acid; In diethyl ether; dichloromethane;

DOI:10.1021/jo00278a013

upstream raw materials:

((E)-3,3-Dimethyl-but-1-enyl)-trimethyl-silane

(Z)-1-(trimethylsilyl)-3,3-dimethyl-1-butene

(3,3-dimethyl-1-butynyl)trimethylsilane