Phosphorodichloridodithioic acid, propyl ester

Base Information

• Chemical Name: Phosphorodichloridodithioic acid, propyl ester
• CAS No.: 5390-61-4
• Molecular Formula: C3H7 Cl2 P S2
• Molecular Weight: 209.1
• Hs Code.: 2931900090
• European Community (EC) Number: 226-385-7
• DSSTox Substance ID: DTXSID9063823
• Nikkaji Number: J217.940G
• Wikidata: Q81991032
• Mol file: 5390-61-4.mol

Synonyms:5390-61-4;Propyl phosphorodichloridodithioate;Propyl dichlorodithiophosphate;Phosphorodichloridodithioic acid, propyl ester;EINECS 226-385-7;C3H7Cl2PS2;SCHEMBL8943282;C3-H7-Cl2-P-S2;DTXSID9063823;(Propylthio)dichlorophosphine sulfide

Chemical Property of Phosphorodichloridodithioic acid, propyl ester

Chemical Property:

• Vapor Pressure: 0.0419mmHg at 25°C
• Boiling Point: 246.8°Cat760mmHg
• Flash Point: 103°C
• PSA: 108.07000
• Density: 1.424g/cm³
• LogP: -1.04790
• XLogP3: 4
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 3
• Exact Mass: 207.9103850
• Heavy Atom Count: 8
• Complexity: 99.5

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCCSP(=S)(Cl)Cl

Technology Process of Phosphorodichloridodithioic acid, propyl ester

There total 4 articles about Phosphorodichloridodithioic acid, propyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 72.0%

tripropyl tetrathiophosphate (1642-48-4) → propyldichlorodithiophosphate (5390-61-4)

Guidance literature:

With trichlorothiophosphine; at 180 - 190 ℃; for 6h;

DOI:10.1007/BF02495702

Reference yield: 49.0%

1-thiopropane (107-03-9) → propyldichlorodithiophosphate (5390-61-4)

Guidance literature:

With trichlorothiophosphine;

DOI:10.1080/10426509608046418

Reference yield:

O-propyl thiophosphorodichloridate (2523-96-8) → propyldichlorodithiophosphate (5390-61-4)

Guidance literature:

With tetraphosphorus decasulfide; Methyltriphenylphosphonium bromide; Yield given. Multistep reaction; 1.) 140 deg C, 4 h, 2.) 150 deg C, 3 h;

DOI:10.1007/BF00959898

upstream raw materials:

O-propyl thiophosphorodichloridate

1-thiopropane

tripropyl tetrathiophosphate

Downstream raw materials:

C₁₉H₁₅F₁₂N₂PS₂

C₁₅H₁₇N₄O₄PS₂

C₁₇H₁₇F₆N₂PS₂

Refernces

• 1、 Tang, Chu-Chi,Lang, Hui-Fang,He, Zheng-Jie,Chen, Ru-Yu. "Studies on chiral thiophosphoric acids and their derivatives 14. The asymmetric cyclization of (+)-cis-1,2,2-trimethyl-1,3-diaminocyclopentane with thiophosphorodichloridates and o-(4-nitrophenyl)thiophosphorochloridates". . p. 123 - 127. Retrieved 2007/10/03.
• 2、 Artyushin, O. I.,Mastryukova, T. A.,Kabachnik, M. I.. "SYNTHESIS OF ALKYLDICHLORODITHIOPHOSPHATES". . p. 2361 - 2362. Retrieved 2007/10/02.