See R-D-Glucopyranuronamide,O-â-Dglucopyranosyl-( 1f6)-O-[O-[N-(2-hydroxy- 5-oxo-1-cyclopenten-1-yl)-â-D-galactopyranuronamidosyl]-( 1f4)-2-(acetylamino)-2,- 6-dideoxy-â-D-glucopyranosyl-(1f4)]-O-2- (acetylamino)-2-deoxy-â-D-glucopyranosyl- (1f2)-4-C-methyl-,3-carbamate 1-[(2R)-2-carboxy-2-[[(2Z,6E,13E)-3,8,8,14,- 18-pentamethyl-11-methylene-2,6,13,17- nonadecatetraenyl]oxy]ethyl hydrogen phosphate]

Base Information

• Chemical Name: See R-D-Glucopyranuronamide,O-â-Dglucopyranosyl-( 1f6)-O-[O-[N-(2-hydroxy- 5-oxo-1-cyclopenten-1-yl)-â-D-galactopyranuronamidosyl]-( 1f4)-2-(acetylamino)-2,- 6-dideoxy-â-D-glucopyranosyl-(1f4)]-O-2- (acetylamino)-2-deoxy-â-D-glucopyranosyl- (1f2)-4-C-methyl-,3-carbamate 1-[(2R)-2-carboxy-2-[[(2Z,6E,13E)-3,8,8,14,- 18-pentamethyl-11-methylene-2,6,13,17- nonadecatetraenyl]oxy]ethyl hydrogen phosphate]
• CAS No.: 76095-39-1

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Chemical Property of See R-D-Glucopyranuronamide,O-â-Dglucopyranosyl-( 1f6)-O-[O-[N-(2-hydroxy- 5-oxo-1-cyclopenten-1-yl)-â-D-galactopyranuronamidosyl]-( 1f4)-2-(acetylamino)-2,- 6-dideoxy-â-D-glucopyranosyl-(1f4)]-O-2- (acetylamino)-2-deoxy-â-D-glucopyranosyl- (1f2)-4-C-methyl-,3-carbamate 1-[(2R)-2-carboxy-2-[[(2Z,6E,13E)-3,8,8,14,- 18-pentamethyl-11-methylene-2,6,13,17- nonadecatetraenyl]oxy]ethyl hydrogen phosphate]

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Cobalt-catalysed hydrovinylation as the key step in a short synthesis of moenocinol

10.1039/b822023a

The research focuses on the development of an efficient and atom-economic synthesis of moenocinol, the aglycone of moenomycin A, using a cobalt-catalysed 1,4-hydrovinylation reaction as the key step. The purpose of this study was to create a straightforward and convergent synthesis of moenocinol, which is a complex molecule with potential pharmaceutical applications. The researchers achieved this by utilizing a cobalt(I)-catalysed 1,4-hydrovinylation reaction that is both regio- and chemoselective, allowing for the formation of 1,4-diene subunits with high yield and excellent regioselectivity. The study concluded that this cobalt-catalysed approach offers the shortest route to moenocinol to date, with a total of five steps in the longest linear sequence starting from 5 and in seven total steps, marking a significant advancement in the synthesis of complex natural product-like structures.

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