2-(azidomethyl)phenyllead triacetate

Base Information

• Chemical Name: 2-(azidomethyl)phenyllead triacetate
• CAS No.: 912281-94-8
• Molecular Formula: C₁₃H₁₅N₃O₆Pb
• Molecular Weight: 516.479
• Mol file: 912281-94-8.mol

Synonyms:2-(azidomethyl)phenyllead triacetate

Chemical Property of 2-(azidomethyl)phenyllead triacetate

Chemical Property:

Purity/Quality:

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MSDS Files:

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Technology Process of 2-(azidomethyl)phenyllead triacetate

There total 1 articles about 2-(azidomethyl)phenyllead triacetate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 52.0%

lead(IV) tetraacetate (546-67-8) + 2-(azidomethyl)phenylboronic acid (745835-05-6) → 2-(azidomethyl)phenyllead triacetate (912281-94-8)

Guidance literature:

mercury(II) diacetate; In chloroform; addn. dropwise soln. of 2-(azidomethyl)phenylboronic acid in CHCl3 in inert atmosphere at 35°C to stirred mixt. of Pb(CH3COO)4 and Hg(CH3COO)2 in anhyd. CHCl3; keeping at this temp. for 1 h; stirring at ca. 20°C for 20 h; filtration through Celite, washing of Celite layer with CHCl3, removal of solvent under reduced pressure, dilution with pentane-ether (1:1); vigorous stirring in ice bath; removal of solvent; recrystn. from CH2Cl2-light petroleum (1:1); elem. anal.;

DOI:10.1007/s11172-006-0011-y

Reference yield: 52.0%

2-(azidomethyl)phenyllead triacetate (912281-94-8) + acetylacetone (123-54-6,81235-32-7) → 3-(2-azidomethylphenyl)pentane-2,4-dione

Guidance literature:

With pyridine; In chloroform; at 40 ℃; for 1h;

DOI:10.1007/s11172-006-0011-y

Reference yield: 50.0%

2-(azidomethyl)phenyllead triacetate (912281-94-8) + 4-hydroxy-5,6,7-trimethoxychromen-2-one (68061-76-7) → 3-(2-azidomethylphenyl)-4-hydroxy-5,6,7-trimethoxycoumarin

Guidance literature:

With pyridine; In chloroform; at 40 ℃; for 1h;

DOI:10.1007/s11172-006-0011-y

upstream raw materials:

lead(IV) tetraacetate

2-(azidomethyl)phenylboronic acid