(3S,3'R,4'S)-1-benzyl-3-(4,5-dihydroxypent-1-en-3-yl)pyrrolidine-2-thione

Base Information

Chemical Name:(3S,3'R,4'S)-1-benzyl-3-(4,5-dihydroxypent-1-en-3-yl)pyrrolidine-2-thione
CAS No.:1082605-56-8
Molecular Formula:C₁₆H₂₁NO₂S
Molecular Weight:291.414
Hs Code.:

Synonyms:(3S,3'R,4'S)-1-benzyl-3-(4,5-dihydroxypent-1-en-3-yl)pyrrolidine-2-thione

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Chemical Property of (3S,3'R,4'S)-1-benzyl-3-(4,5-dihydroxypent-1-en-3-yl)pyrrolidine-2-thione

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Technology Process of (3S,3'R,4'S)-1-benzyl-3-(4,5-dihydroxypent-1-en-3-yl)pyrrolidine-2-thione

There total 19 articles about (3S,3'R,4'S)-1-benzyl-3-(4,5-dihydroxypent-1-en-3-yl)pyrrolidine-2-thione which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

: 1082605-47-7
(3S,1′R,4″S)-1-benzyl-3-[1-(2,2-dimethyl-1,3-dioxolan-4-yl)allyl]pyrrolidine-2-thione

: 1082605-56-8
(3S,3'R,4'S)-1-benzyl-3-(4,5-dihydroxypent-1-en-3-yl)pyrrolidine-2-thione

Guidance literature:: With acetic acid; In water; at 20 ℃; for 24h;
DOI:10.1039/c3ob41580e

Reference yield: 93.0%

: (3S,3′R,4′S)-1-benzyl-3-[4,5-di-(tert-butyldimethylsilanyloxy)-pent-1-en-3-yl]pyrrolidine-2-thione

: 1082605-56-8
(3S,3'R,4'S)-1-benzyl-3-(4,5-dihydroxypent-1-en-3-yl)pyrrolidine-2-thione

Guidance literature:: With acetic acid; In tetrahydrofuran; at 50 ℃;
DOI:10.1039/c3ob41580e

Reference yield:

: 17642-88-5
1-benzyl-2-pyrrolidinethione

: 1082605-56-8
(3S,3'R,4'S)-1-benzyl-3-(4,5-dihydroxypent-1-en-3-yl)pyrrolidine-2-thione

Guidance literature:: Multi-step reaction with 2 steps

1.1: acetonitrile / 96 h / Molecular sieve; Inert atmosphere

1.2: 7 h / 35 - 40 °C / Inert atmosphere; Molecular sieve

2.1: acetic acid / water / 24 h / 20 °C

With acetic acid; In water; acetonitrile; 1.1: |Thio-Claisen Rearrangement / 1.2: |Thio-Claisen Rearrangement;
DOI:10.1039/c3ob41580e