(2,5)-di((selenophen-2-yl)-1,4-phenylene)bis(di(4-hexylphenyl))methanol

Base Information

• Chemical Name: (2,5)-di((selenophen-2-yl)-1,4-phenylene)bis(di(4-hexylphenyl))methanol
• CAS No.: 1448777-70-5
• Molecular Formula: C₆₄H₇₈O₂Se₂
• Molecular Weight: 1037.24
• Mol file: 1448777-70-5.mol

Synonyms:(2,5)-di((selenophen-2-yl)-1,4-phenylene)bis(di(4-hexylphenyl))methanol

Chemical Property of (2,5)-di((selenophen-2-yl)-1,4-phenylene)bis(di(4-hexylphenyl))methanol

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (2,5)-di((selenophen-2-yl)-1,4-phenylene)bis(di(4-hexylphenyl))methanol

There total 2 articles about (2,5)-di((selenophen-2-yl)-1,4-phenylene)bis(di(4-hexylphenyl))methanol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

1-bromo-4-n-hexylbenzene (23703-22-2) + 2,5-di(selenophen-2-yl)terephthalic acid ethyl ester (1448777-69-2) → (2,5)-di((selenophen-2-yl)-1,4-phenylene)bis(di(4-hexylphenyl))methanol (1448777-70-5)

Guidance literature:

1-bromo-4-n-hexylbenzene; With n-butyllithium; In tetrahydrofuran; hexane; at -78 ℃; for 1h; Inert atmosphere;

2,5-di(selenophen-2-yl)terephthalic acid ethyl ester; In tetrahydrofuran; hexane; at -78 - 20 ℃; Inert atmosphere;

DOI:10.1021/cm401586t

Reference yield:

1-bromo-4-n-hexylbenzene (23703-22-2) → (2,5)-di((selenophen-2-yl)-1,4-phenylene)bis(di(4-hexylphenyl))methanol (1448777-70-5)

Guidance literature:

1-bromo-4-n-hexylbenzene; With n-butyllithium; In tetrahydrofuran; hexane; at -78 ℃; for 1h;

In tetrahydrofuran; hexane; at -78 - 20 ℃;

DOI:10.1021/ma401415g

Reference yield: 78.0%

(2,5)-di((selenophen-2-yl)-1,4-phenylene)bis(di(4-hexylphenyl))methanol (1448777-70-5) → 4,4,9,9-tetrakis(4-hexylphenyl)indaceno[1,2-b:5,6-b']diselenophene (1448777-71-6)

Guidance literature:

With hydrogenchloride; acetic acid; In water; for 3h; Reflux;

DOI:10.1021/cm401586t

upstream raw materials:

1-bromo-4-n-hexylbenzene

2,5-di(selenophen-2-yl)terephthalic acid ethyl ester

Downstream raw materials:

4,4,9,9-tetrakis(4-hexylphenyl)indaceno[1,2-b:5,6-b']diselenophene