allyl 2-azido-3,4-di-O-benzyl-6-O-tert-butyldimethylsilyl-2-deoxy-α-D-glucopyranoside

Base Information

Chemical Name:allyl 2-azido-3,4-di-O-benzyl-6-O-tert-butyldimethylsilyl-2-deoxy-α-D-glucopyranoside
CAS No.:152756-63-3
Molecular Formula:C₂₉H₄₁N₃O₅Si
Molecular Weight:539.747
Hs Code.:

Synonyms:allyl 2-azido-3,4-di-O-benzyl-6-O-tert-butyldimethylsilyl-2-deoxy-α-D-glucopyranoside

Suppliers and Price of allyl 2-azido-3,4-di-O-benzyl-6-O-tert-butyldimethylsilyl-2-deoxy-α-D-glucopyranoside

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of allyl 2-azido-3,4-di-O-benzyl-6-O-tert-butyldimethylsilyl-2-deoxy-α-D-glucopyranoside

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of allyl 2-azido-3,4-di-O-benzyl-6-O-tert-butyldimethylsilyl-2-deoxy-α-D-glucopyranoside

There total 2 articles about allyl 2-azido-3,4-di-O-benzyl-6-O-tert-butyldimethylsilyl-2-deoxy-α-D-glucopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 36.0%

: 106-95-6
allyl bromide

: 2-azido-3,4-di-O-benzyl-6-O-tert-butyldimethylsilyl-2-deoxy-D-glucopyranose

: allyl 2-azido-3,4-di-O-benzyl-6-O-tert-butyldimethylsilyl-2-deoxy-β-D-glucopyranoside

: 152756-63-3
allyl 2-azido-3,4-di-O-benzyl-6-O-tert-butyldimethylsilyl-2-deoxy-α-D-glucopyranoside

Guidance literature:: With sodium hydride; In N,N-dimethyl-formamide; at -30 ℃; for 6h;
DOI:10.1016/0008-6215(93)84029-6

Reference yield:

: 129840-37-5
1,5-anhydro-3,4-di-O-benzyl-6-O-(tert-butyldimethylsilyl)-2-deoxy-D-arabino-hex-1-enitol

: 152756-63-3
allyl 2-azido-3,4-di-O-benzyl-6-O-tert-butyldimethylsilyl-2-deoxy-α-D-glucopyranoside

Guidance literature:: Multi-step reaction with 2 steps

1: 1) NaN₃, ceric ammonium nitrate, 2) NaNO₂ / 1) MeCN, -40 deg C, 24 h, 2) dioxan, H₂O, 75 deg C, 8 h

2: 36 percent / NaH / dimethylformamide / 6 h / -30 °C

With sodium azide; ammonium cerium(IV) nitrate; sodium hydride; sodium nitrite; In N,N-dimethyl-formamide;
DOI:10.1016/0008-6215(93)84029-6

Reference yield: 93.0%

: 152756-63-3
allyl 2-azido-3,4-di-O-benzyl-6-O-tert-butyldimethylsilyl-2-deoxy-α-D-glucopyranoside

: 152756-64-4
allyl 2-azido-3,4-di-O-benzyl-2-deoxy-α-D-glucopyranoside

Guidance literature:: With tetrabutyl ammonium fluoride; acetic acid; In tetrahydrofuran; for 1h; -10 deg C to r.t.;
DOI:10.1016/0008-6215(93)84029-6