Methyl 3-O-methyl-2,6-bis-O-(phenylmethyl)-alpha-D-glucopyranoside

Base Information

Chemical Name:Methyl 3-O-methyl-2,6-bis-O-(phenylmethyl)-alpha-D-glucopyranoside
CAS No.:245366-76-1
Molecular Formula:C₂₂H₂₈O₆
Molecular Weight:388.461
Hs Code.:
European Community (EC) Number:607-397-5
DSSTox Substance ID:DTXSID001177311

Synonyms:SCHEMBL3151671;DTXSID001177311;Methyl 3-O-methyl-2,6-bis-O-(phenylmethyl)-alpha-D-glucopyranoside;245366-76-1

Suppliers and Price of Methyl 3-O-methyl-2,6-bis-O-(phenylmethyl)-alpha-D-glucopyranoside

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

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Chemical Property of Methyl 3-O-methyl-2,6-bis-O-(phenylmethyl)-alpha-D-glucopyranoside

Chemical Property:

XLogP3:2
Hydrogen Bond Donor Count:1
Hydrogen Bond Acceptor Count:6
Rotatable Bond Count:9
Exact Mass:388.18858861
Heavy Atom Count:28
Complexity:421

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:COC1C(C(OC(C1OCC2=CC=CC=C2)OC)COCC3=CC=CC=C3)O
Isomeric SMILES:CO[C@H]1[C@@H]([C@H](O[C@@H]([C@@H]1OCC2=CC=CC=C2)OC)COCC3=CC=CC=C3)O

Technology Process of Methyl 3-O-methyl-2,6-bis-O-(phenylmethyl)-alpha-D-glucopyranoside

There total 2 articles about Methyl 3-O-methyl-2,6-bis-O-(phenylmethyl)-alpha-D-glucopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

: 189390-16-7
methyl 2-O-benzyl-4,6-O-benzylidene-3-O-methyl-α-D-glucopyranoside

: 245366-76-1
methyl 2,6-di-O-benzyl-3-O-methyl-α-D-glucopyranoside

Guidance literature:: With trifluorormethanesulfonic acid; sodium cyanoborohydride; In tetrahydrofuran; at 0 ℃; for 0.25h;
DOI:10.1002/ejoc.201100861

Reference yield:

: 76375-66-1
methyl 2-O-benzyl-4,6-O-benzylidene-α-D-glucopyranoside

: 245366-76-1
methyl 2,6-di-O-benzyl-3-O-methyl-α-D-glucopyranoside

Guidance literature:: Multi-step reaction with 2 steps

1: 79 percent / NaH / dimethylformamide / 1 h

2: 70 percent / HBF₄, NaBH₃CN / tetrahydrofuran; diethyl ether / 1.25 h

With tetrafluoroboric acid; sodium hydride; sodium cyanoborohydride; In tetrahydrofuran; diethyl ether; N,N-dimethyl-formamide;
DOI:10.1021/jm960726z