CuN(CH₃)2CH₂CH₂(CH₃)2N(CO)HOCH₃⁽¹⁺⁾*B(C₆H₅)4^(1-)

Base Information

• Chemical Name: CuN(CH₃)2CH₂CH₂(CH₃)2N(CO)HOCH₃⁽¹⁺⁾*B(C₆H₅)4^(1-)
• CAS No.: 76467-84-0
• Molecular Formula: C₈H₂₀CuN₂O₂*C₂₄H₂₀B
• Molecular Weight: 559.039
• Mol file: 76467-84-0.mol

Synonyms:CuN(CH₃)2CH₂CH₂(CH₃)2N(CO)HOCH₃⁽¹⁺⁾*B(C₆H₅)4^(1-)

Chemical Property of CuN(CH₃)2CH₂CH₂(CH₃)2N(CO)HOCH₃⁽¹⁺⁾*B(C₆H₅)4^(1-)

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of CuN(CH₃)2CH₂CH₂(CH₃)2N(CO)HOCH₃⁽¹⁺⁾*B(C₆H₅)4^(1-)

There total 1 articles about CuN(CH₃)2CH₂CH₂(CH₃)2N(CO)HOCH₃⁽¹⁺⁾*B(C₆H₅)4^(1-) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 35.0%

{Cu(μ-O2CC6H5)}4 + N,N,N,N,-tetramethylethylenediamine (110-18-9) + sodium tetraphenyl borate (143-66-8) → CuN(CH3)2CH2CH2(CH3)2N(CO)HOCH3(1+)*B(C6H5)4(1-) (76467-84-0)

Guidance literature:

With CO; In methanol; byproducts: CO; complex was treated with CO in MeOH; cooling to -40°C, addn. of tmen; addn. of soln. of NaBPh4 at -30.degree,C; formed white solid converted into yellow solid; filtration (N2), drying at -30°C (CO); elem. anal.;

DOI:10.1021/ja00379a009

Reference yield: 56.4%

N,N,N,N,-tetramethylethylenediamine (110-18-9) + CuN(CH3)2CH2CH2(CH3)2N(CO)HOCH3(1+)*B(C6H5)4(1-) (76467-84-0) → [Cu(N,N,N',N'-tetramethylethylenediamine)2]BPh4 (81770-63-0)

Guidance literature:

In methanol; byproducts: CO; stirring at room temp. for a few h (N2); elem. anal.;

DOI:10.1021/ja00379a009

Reference yield:

CuN(CH3)2CH2CH2(CH3)2N(CO)HOCH3(1+)*B(C6H5)4(1-) (76467-84-0) → [Cu2(N,N,N',N'-tetramethylethylenediamine)2(CO)2(μ-MeCO2)]BPh4 (81770-65-2)

Guidance literature:

With NaOAc; In methanol; stirring for 12 h (CO); concn. (CO), cooling at -80°C for 12 h; elem. anal.;

DOI:10.1021/ja00379a009

upstream raw materials:

N,N,N,N,-tetramethylethylenediamine

sodium tetraphenyl borate

Downstream raw materials:

[Cu(N,N,N',N'-tetramethylethylenediamine)]BPh₄

[Cu2(N,N,N',N'-tetramethylethylenediamine)2(CO)2(μ-MeCO2)]BPh4

[Cu2(tmen)2(μ-CO)(μ-PhCO2)](B(C6H5)4)

[Cu(N,N,N',N'-tetramethylethylenediamine)2]BPh₄