(E)-1-(4-(6-bromohexyloxy)phenyl)-2-(4'-(dodecyloxy)-3'-methoxybiphenyl-4-yl)diazene

Base Information

Chemical Name:(E)-1-(4-(6-bromohexyloxy)phenyl)-2-(4'-(dodecyloxy)-3'-methoxybiphenyl-4-yl)diazene
CAS No.:1373207-58-9
Molecular Formula:C₃₇H₅₁BrN₂O₃
Molecular Weight:651.728
Hs Code.:

Synonyms:(E)-1-(4-(6-bromohexyloxy)phenyl)-2-(4'-(dodecyloxy)-3'-methoxybiphenyl-4-yl)diazene

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Chemical Property of (E)-1-(4-(6-bromohexyloxy)phenyl)-2-(4'-(dodecyloxy)-3'-methoxybiphenyl-4-yl)diazene

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Technology Process of (E)-1-(4-(6-bromohexyloxy)phenyl)-2-(4'-(dodecyloxy)-3'-methoxybiphenyl-4-yl)diazene

There total 7 articles about (E)-1-(4-(6-bromohexyloxy)phenyl)-2-(4'-(dodecyloxy)-3'-methoxybiphenyl-4-yl)diazene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

: 1373207-48-7
(E)-1-(4-(6-bromohexyloxy)phenyl)-2-(4-bromophenyl)diazene

: 210368-01-7
3-methoxy-4-(dodecyloxy)phenylboronic acid

: 1373207-58-9
(E)-1-(4-(6-bromohexyloxy)phenyl)-2-(4'-(dodecyloxy)-3'-methoxybiphenyl-4-yl)diazene

Guidance literature:: With tetrakis(triphenylphosphine) palladium⁽⁰⁾; sodium carbonate; In tetrahydrofuran; at 65 ℃;
DOI:10.1016/j.polymer.2012.03.024

Reference yield:

: 3035-94-7
(E)-4-((4-bromophenyl)diazenyl)phenol

: 1373207-58-9
(E)-1-(4-(6-bromohexyloxy)phenyl)-2-(4'-(dodecyloxy)-3'-methoxybiphenyl-4-yl)diazene

Guidance literature:: Multi-step reaction with 2 steps

1: potassium carbonate; potassium iodide / acetone / 48 h / Reflux

2: tetrakis(triphenylphosphine) palladium⁽⁰⁾; sodium carbonate / tetrahydrofuran / 65 °C

With tetrakis(triphenylphosphine) palladium⁽⁰⁾; sodium carbonate; potassium carbonate; potassium iodide; In tetrahydrofuran; acetone;
DOI:10.1016/j.polymer.2012.03.024

Reference yield:

: 7368-78-7
4-bromoguaiacol

: 1373207-58-9
(E)-1-(4-(6-bromohexyloxy)phenyl)-2-(4'-(dodecyloxy)-3'-methoxybiphenyl-4-yl)diazene

Guidance literature:: Multi-step reaction with 3 steps

1.1: potassium carbonate; potassium iodide / acetone / 48 h / Reflux

2.1: n-butyllithium; Triisopropyl borate / tetrahydrofuran; hexane / 1.5 h / -78 - -70 °C

2.2: 20 °C

2.3: 1.5 h

3.1: tetrakis(triphenylphosphine) palladium⁽⁰⁾; sodium carbonate / tetrahydrofuran / 65 °C

With tetrakis(triphenylphosphine) palladium⁽⁰⁾; n-butyllithium; Triisopropyl borate; sodium carbonate; potassium carbonate; potassium iodide; In tetrahydrofuran; hexane; acetone;
DOI:10.1016/j.polymer.2012.03.024