methyl [2,3-di-O-benzyl-4-O-(2'-naphthyl)methyl-6-deoxy-6-C-(ethyl sulfonatomethyl)-α-D-glucopyranosyl]-(1→4)-[methyl (2-O-acetyl-3-O-methyl-α-L-idopyranosyl)uronate]-(1→4)-2,3-di-O-benzyl-6-deoxy-6-C-(ethyl sulfonatomethyl)-α-D-glucopyranoside

Base Information

• Chemical Name: methyl [2,3-di-O-benzyl-4-O-(2'-naphthyl)methyl-6-deoxy-6-C-(ethyl sulfonatomethyl)-α-D-glucopyranosyl]-(1→4)-[methyl (2-O-acetyl-3-O-methyl-α-L-idopyranosyl)uronate]-(1→4)-2,3-di-O-benzyl-6-deoxy-6-C-(ethyl sulfonatomethyl)-α-D-glucopyranoside
• CAS No.: 1590422-08-4
• Molecular Formula: C₆₈H₈₂O₂₂S₂
• Molecular Weight: 1315.52
• Mol file: 1590422-08-4.mol

Synonyms:methyl [2,3-di-O-benzyl-4-O-(2'-naphthyl)methyl-6-deoxy-6-C-(ethyl sulfonatomethyl)-α-D-glucopyranosyl]-(1→4)-[methyl (2-O-acetyl-3-O-methyl-α-L-idopyranosyl)uronate]-(1→4)-2,3-di-O-benzyl-6-deoxy-6-C-(ethyl sulfonatomethyl)-α-D-glucopyranoside

Chemical Property of methyl [2,3-di-O-benzyl-4-O-(2'-naphthyl)methyl-6-deoxy-6-C-(ethyl sulfonatomethyl)-α-D-glucopyranosyl]-(1→4)-[methyl (2-O-acetyl-3-O-methyl-α-L-idopyranosyl)uronate]-(1→4)-2,3-di-O-benzyl-6-deoxy-6-C-(ethyl sulfonatomethyl)-α-D-glucopyranoside

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of methyl [2,3-di-O-benzyl-4-O-(2'-naphthyl)methyl-6-deoxy-6-C-(ethyl sulfonatomethyl)-α-D-glucopyranosyl]-(1→4)-[methyl (2-O-acetyl-3-O-methyl-α-L-idopyranosyl)uronate]-(1→4)-2,3-di-O-benzyl-6-deoxy-6-C-(ethyl sulfonatomethyl)-α-D-glucopyranoside

There total 1 articles about methyl [2,3-di-O-benzyl-4-O-(2'-naphthyl)methyl-6-deoxy-6-C-(ethyl sulfonatomethyl)-α-D-glucopyranosyl]-(1→4)-[methyl (2-O-acetyl-3-O-methyl-α-L-idopyranosyl)uronate]-(1→4)-2,3-di-O-benzyl-6-deoxy-6-C-(ethyl sulfonatomethyl)-α-D-glucopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

C36H42O7S2 (1456718-96-9) + methyl [methyl (2-O-acetyl-3-O-methyl-α-l-idopyranosyl)uronate]-(1→4)-2,3-di-O-benzyl-6-deoxy-6-C-(ethyl sulfonatomethyl)-α-D-glucopyranoside (1590422-07-3) → methyl [2,3-di-O-benzyl-4-O-(2'-naphthyl)methyl-6-deoxy-6-C-(ethyl sulfonatomethyl)-α-D-glucopyranosyl]-(1→4)-[methyl (2-O-acetyl-3-O-methyl-α-L-idopyranosyl)uronate]-(1→4)-2,3-di-O-benzyl-6-deoxy-6-C-(ethyl sulfonatomethyl)-α-D-glucopyranoside (1590422-08-4)

Guidance literature:

C₃₆H₄₂O₇S₂; methyl [methyl (2-O-acetyl-3-O-methyl-α-l-idopyranosyl)uronate]-(1→4)-2,3-di-O-benzyl-6-deoxy-6-C-(ethyl sulfonatomethyl)-α-D-glucopyranoside; In dichloromethane; at -60 ℃; for 0.5h; Molecular sieve; Inert atmosphere;

With N-iodo-succinimide; toluene-4-sulfonic acid; In tetrahydrofuran; dichloromethane; at -50 ℃; for 3h; Molecular sieve; Inert atmosphere;

DOI:10.1016/j.carres.2014.02.012

Reference yield: 79.0%

methyl [2,3-di-O-benzyl-4-O-(2'-naphthyl)methyl-6-deoxy-6-C-(ethyl sulfonatomethyl)-α-D-glucopyranosyl]-(1→4)-[methyl (2-O-acetyl-3-O-methyl-α-L-idopyranosyl)uronate]-(1→4)-2,3-di-O-benzyl-6-deoxy-6-C-(ethyl sulfonatomethyl)-α-D-glucopyranoside (1590422-08-4) → methyl [2,3-di-O-benzyl-6-deoxy-6-C-(ethyl sulfonatomethyl)-α-D-glucopyranosyl]-(1→4)-[methyl (2-O-acetyl-3-O-methyl-α-l-idopyranosyl)uronate]-(1→4)-2,3-di-O-benzyl-6-deoxy-6-C-(ethyl sulfonatomethyl)-α-D-glucopyranoside (1590422-09-5)

Guidance literature:

With water; 2,3-dicyano-5,6-dichloro-p-benzoquinone; In dichloromethane; at 20 ℃; for 0.5h;

DOI:10.1016/j.carres.2014.02.012

upstream raw materials:

C₃₆H₄₂O₇S₂

methyl [methyl (2-O-acetyl-3-O-methyl-α-l-idopyranosyl)uronate]-(1→4)-2,3-di-O-benzyl-6-deoxy-6-C-(ethyl sulfonatomethyl)-α-D-glucopyranoside

Downstream raw materials:

methyl [2,3-di-O-benzyl-6-deoxy-6-C-(ethyl sulfonatomethyl)-α-D-glucopyranosyl]-(1→4)-[methyl (2-O-acetyl-3-O-methyl-α-l-idopyranosyl)uronate]-(1→4)-2,3-di-O-benzyl-6-deoxy-6-C-(ethyl sulfonatomethyl)-α-D-glucopyranoside