(η2-7,8-benzoquinolinato)aquahydridobis(triphenylphosphine)iridium(III) hexafluoroantimoniate

Base Information

Chemical Name:(η2-7,8-benzoquinolinato)aquahydridobis(triphenylphosphine)iridium(III) hexafluoroantimoniate
CAS No.:98938-36-4
Molecular Formula:C₄₉H₄₁IrNOP₂*F₆Sb
Molecular Weight:1149.78
Hs Code.:

Synonyms:(η2-7,8-benzoquinolinato)aquahydridobis(triphenylphosphine)iridium(III) hexafluoroantimoniate

Suppliers and Price of (η2-7,8-benzoquinolinato)aquahydridobis(triphenylphosphine)iridium(III) hexafluoroantimoniate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of (η2-7,8-benzoquinolinato)aquahydridobis(triphenylphosphine)iridium(III) hexafluoroantimoniate

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of (η2-7,8-benzoquinolinato)aquahydridobis(triphenylphosphine)iridium(III) hexafluoroantimoniate

There total 3 articles about (η2-7,8-benzoquinolinato)aquahydridobis(triphenylphosphine)iridium(III) hexafluoroantimoniate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

: 230-27-3
7,8-benzoquinoline

: 91410-27-4
{Ir(COD)(PPh₃)2}SbF₆

: 98938-36-4
(η2-7,8-benzoquinolinato)aquahydridobis(triphenylphosphine)iridium(III) hexafluoroantimoniate

Guidance literature:: With hydrogen; In dichloromethane; to (Ir(cod)(PPh3)2)SbF6 in moist CH2Cl2 was added 7,8-benzoquinoline and H2 gas bubbled through the mixt. at 0°C for 30 min; product was crystd. from Et2O-heptane and recrystd. from CH2Cl2/Et2O-heptane; NMR;
DOI:10.1021/ja00274a030

Reference yield: 85.0%

: 230-27-3
7,8-benzoquinoline

: 91410-27-4
{Ir(1,5-cyclooctadiene)(PPh₃)2}SbF₆

: 98938-36-4
(η2-7,8-benzoquinolinato)aquahydridobis(triphenylphosphine)iridium(III) hexafluoroantimoniate

Guidance literature:: With H₂; In dichloromethane; Addn. of 7,8-benzoquinoline to a soln. of (Ir(1,5-cyclooctadiene)(PPh3)2)SbF6 in CH2Cl2; H2 (1 atm.) was passed through the soln. for 30 min. at 0°C; The light yellow soln. was crystallized with diethyl ether; recrystn. with CH2Cl2/Et2O. Detected by 1H-NMR, IR, elem. anal. and X-ray diffraction;