RuH₆(PCy₃)2

Base Information

Chemical Name:RuH₆(PCy₃)2
CAS No.:85435-92-3
Molecular Formula:C₃₆H₇₂P₂Ru
Molecular Weight:667.985
Hs Code.:

Synonyms:RuH₆(PCy₃)2

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Chemical Property of RuH₆(PCy₃)2

Chemical Property:

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Technology Process of RuH₆(PCy₃)2

There total 2 articles about RuH₆(PCy₃)2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 60.0%

: 42516-72-3
(η6-1,3,5-cyclooctatriene)(η4-1,5-cyclooctadiene)ruthenium(0)

: 2622-14-2
tricyclohexylphosphine

: 85435-92-3
RuH₆(PCy₃)2

Guidance literature:: With hydrogen; In hexane; 1 equiv of Ru complex adding to a soln. of 2 equiv of the phosphine, stirring for 15 min at room temp., H2 bubbling slowly through the soln. for 3 h, the white ppt. filtering off; identified by IR and NMR spectra;

Reference yield: 40.0%

: 42516-72-3
(η6-1,3,5-cyclooctatriene)(η4-1,5-cyclooctadiene)ruthenium(0)

: 2622-14-2
tricyclohexylphosphine

: 85435-92-3
RuH₆(PCy₃)2

: 91946-50-8
RuH₄(P(C₆H₁₁)3)3

Guidance literature:: In hexane; Ru complex was added to a soln. of 0.5 equiv of the phosphine and stirred at room temp. for 3 h to give a pale red soln. with some white ppt. of hexahydride complex which was filtered off, the soln. was concd. in vacuo and cooled to -78°C; identified by elem. anal. and IR spectrum;

Reference yield: 80.0%

: 85435-92-3
RuH₆(PCy₃)2

: 97570-15-5
Ru(H₂O)5(P(C₆H₁₁)3)⁽²⁺⁾*2BF₄^(1-)=Ru(H₂O)5(P(C₆H₁₁)3)(BF₄)2

Guidance literature:: With tetrafluoroboric acid; water; In tetrahydrofuran; byproducts: H2; adding of 35% aq. HBF4 to a soln. of the complex, stirring for 30 min, evapg. to dryness; purified by recrystallization from CH2Cl2-Et2O, identified by elem. anal., IR and NMR spectra;