N-bis(4-methoxyphenyl)methylene-O-(2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyl)-L-serinate

Base Information

• Chemical Name: N-bis(4-methoxyphenyl)methylene-O-(2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyl)-L-serinate
• CAS No.: 936115-46-7
• Molecular Formula: C₃₉H₄₃NO₁₄
• Molecular Weight: 749.769
• Mol file: 936115-46-7.mol

Synonyms:N-bis(4-methoxyphenyl)methylene-O-(2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyl)-L-serinate

Chemical Property of N-bis(4-methoxyphenyl)methylene-O-(2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyl)-L-serinate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of N-bis(4-methoxyphenyl)methylene-O-(2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyl)-L-serinate

There total 12 articles about N-bis(4-methoxyphenyl)methylene-O-(2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyl)-L-serinate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 84.0%

benzyl N-bis(4-methoxyphenyl)methylene-L-serinate (936115-45-6) + β-D-glucose pentaacetate (604-69-3) → N-bis(4-methoxyphenyl)methylene-O-(2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyl)-L-serinate (936115-46-7)

Guidance literature:

With boron trifluoride diethyl etherate; In dichloromethane; at 20 ℃; for 24h;

Reference yield: 65.0%

C25H25NO5 (1253053-57-4) + β-D-glucose pentaacetate (604-69-3) → N-bis(4-methoxyphenyl)methylene-O-(2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyl)-L-serinate (936115-46-7)

Guidance literature:

With boron trifluoride diethyl etherate; In acetonitrile; at 40 - 60 ℃; for 0.0375h; Microwave irradiation;

DOI:10.1080/07328303.2010.508295

Reference yield:

C25H25NO5 (1253053-57-4) + β-D-glucose pentaacetate (604-69-3) → N-bis(4-methoxyphenyl)methylene-O-(2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyl)-L-serinate (936115-46-7) + C39H43NO14 (1253053-70-1)

Guidance literature:

With boron trifluoride diethyl etherate; In dichloromethane; at 20 ℃; for 40h; optical yield given as %de;

DOI:10.1080/07328303.2010.508295

upstream raw materials:

benzyl N-bis(4-methoxyphenyl)methylene-L-serinate

β-D-glucose pentaacetate

1-bromo-4-methoxy-benzene

C₂₅H₂₅NO₅

Downstream raw materials:

C₂₄H₃₁NO₁₂

N-9-fluorenylmethoxycarbonyl-O-(2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyl)-L-serine benzyl ester