Technology Process of (1Z)-N-benzylidene-1-(2-(3-butenyl)phenyl)-1-propen-2-amine N-oxide
There total 5 articles about (1Z)-N-benzylidene-1-(2-(3-butenyl)phenyl)-1-propen-2-amine N-oxide which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
(Z)-N-benzylidene-1-(2-(3-butenyl)phenyl)-1-(phenylselanyl)propan-2-amine N-oxide;
With
diisopropylamine; 3-chloro-benzenecarboperoxoic acid;
In
dichloromethane;
at -78 - 20 ℃;
With
diisopropylamine;
In
benzene;
at 60 ℃;
for 0.5h;
DOI:10.1021/jo060975n
- Guidance literature:
-
Multi-step reaction with 4 steps
1.1: sodium borohydride / ethanol / 0.17 h
1.2: ethanol / 1 h / -75 °C
1.3: glacial acetic acid / ethanol / 1 h / 20 °C
2.1: aluminum amalgam / ethyl acetate; H2O / 0.5 h / 20 °C
3.1: ethanol / 2 h / 20 °C
4.1: meta-chloroperoxybenzoic acid; diisopropylamine / CH2Cl2 / -78 - 20 °C
4.2: 89 percent / diisopropylamine / benzene / 0.5 h / 60 °C
With
sodium tetrahydroborate; aluminium amalgam; diisopropylamine; 3-chloro-benzenecarboperoxoic acid;
In
ethanol; dichloromethane; water; ethyl acetate;
DOI:10.1021/jo060975n
- Guidance literature:
-
Multi-step reaction with 3 steps
1.1: aluminum amalgam / ethyl acetate; H2O / 0.5 h / 20 °C
2.1: ethanol / 2 h / 20 °C
3.1: meta-chloroperoxybenzoic acid; diisopropylamine / CH2Cl2 / -78 - 20 °C
3.2: 89 percent / diisopropylamine / benzene / 0.5 h / 60 °C
With
aluminium amalgam; diisopropylamine; 3-chloro-benzenecarboperoxoic acid;
In
ethanol; dichloromethane; water; ethyl acetate;
DOI:10.1021/jo060975n
