4'-(azidocarbonyl)phenyl 4-(tert-butyldiphenylsiloxymethyl)phenyl ketone

Base Information

Chemical Name:4'-(azidocarbonyl)phenyl 4-(tert-butyldiphenylsiloxymethyl)phenyl ketone
CAS No.:162896-94-8
Molecular Formula:C₃₁H₂₉N₃O₃Si
Molecular Weight:519.675
Hs Code.:

Synonyms:4'-(azidocarbonyl)phenyl 4-(tert-butyldiphenylsiloxymethyl)phenyl ketone

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Chemical Property of 4'-(azidocarbonyl)phenyl 4-(tert-butyldiphenylsiloxymethyl)phenyl ketone

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Technology Process of 4'-(azidocarbonyl)phenyl 4-(tert-butyldiphenylsiloxymethyl)phenyl ketone

There total 10 articles about 4'-(azidocarbonyl)phenyl 4-(tert-butyldiphenylsiloxymethyl)phenyl ketone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 82.0%

: 162896-93-7
4-<4'-(tert-butyldiphenylsiloxymethyl)phenylcarbonyl>benzoic acid

: 162896-94-8
4'-(azidocarbonyl)phenyl 4-(tert-butyldiphenylsiloxymethyl)phenyl ketone

Guidance literature:: With diphenyl phosphoryl azide; triethylamine; In tetrahydrofuran; for 18h; Ambient temperature;

Reference yield:

: 611-97-2
bis(p-methylphenyl)-methanone

: 162896-94-8
4'-(azidocarbonyl)phenyl 4-(tert-butyldiphenylsiloxymethyl)phenyl ketone

Guidance literature:: Multi-step reaction with 6 steps

1: 1.) conc. H₂SO₄, CrO₃, 2.) conc. H₂SO₄ / 1.) acetic anhydride, room temperature, 2 h, 2.) EtOH, H₂O, reflux, 30 min

2: 44 percent / LiAl(t-BuO)3H / tetrahydrofuran / 1.) 0 deg C, 2 h, 2.) room temperature, 18 h

3: 36 percent / imidazole / dimethylformamide / 18 h / Ambient temperature

4: 89 percent / MnO₂ / CHCl₃ / 18 h / Ambient temperature

5: 63 percent / KMnO₄, 5percent NaH₂PO₄, pH 4-5, 10percent HCl / various solvent(s); H₂O / 0.08 h / Ambient temperature

6: 82 percent / (PhO)2P(O)N₃, Et₃N / tetrahydrofuran / 18 h / Ambient temperature

With 1H-imidazole; chromium(VI) oxide; hydrogenchloride; manganese(IV) oxide; potassium permanganate; sodium dihydrogenphosphate; sulfuric acid; diphenyl phosphoryl azide; lithium tri-t-butoxyaluminum hydride; triethylamine; In tetrahydrofuran; chloroform; water; N,N-dimethyl-formamide;

Reference yield:

: 162896-87-9
bis-(4,4′-formyl)benzophenone

: 162896-94-8
4'-(azidocarbonyl)phenyl 4-(tert-butyldiphenylsiloxymethyl)phenyl ketone

Guidance literature:: Multi-step reaction with 5 steps

1: 44 percent / LiAl(t-BuO)3H / tetrahydrofuran / 1.) 0 deg C, 2 h, 2.) room temperature, 18 h

2: 36 percent / imidazole / dimethylformamide / 18 h / Ambient temperature

3: 89 percent / MnO₂ / CHCl₃ / 18 h / Ambient temperature

4: 63 percent / KMnO₄, 5percent NaH₂PO₄, pH 4-5, 10percent HCl / various solvent(s); H₂O / 0.08 h / Ambient temperature

5: 82 percent / (PhO)2P(O)N₃, Et₃N / tetrahydrofuran / 18 h / Ambient temperature

With 1H-imidazole; hydrogenchloride; manganese(IV) oxide; potassium permanganate; sodium dihydrogenphosphate; diphenyl phosphoryl azide; lithium tri-t-butoxyaluminum hydride; triethylamine; In tetrahydrofuran; chloroform; water; N,N-dimethyl-formamide;