(-)-2,3,6-tri-O-benzyl-5-O-(sulfo)-D-myo-inositol 1,4-O-bis(dibenzyl phosphate)

Base Information

Chemical Name:(-)-2,3,6-tri-O-benzyl-5-O-(sulfo)-D-myo-inositol 1,4-O-bis(dibenzyl phosphate)
CAS No.:1262331-30-5
Molecular Formula:C₅₅H₅₆O₁₅P₂S
Molecular Weight:1051.05
Hs Code.:

Synonyms:(-)-2,3,6-tri-O-benzyl-5-O-(sulfo)-D-myo-inositol 1,4-O-bis(dibenzyl phosphate)

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Chemical Property of (-)-2,3,6-tri-O-benzyl-5-O-(sulfo)-D-myo-inositol 1,4-O-bis(dibenzyl phosphate)

Chemical Property:

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Technology Process of (-)-2,3,6-tri-O-benzyl-5-O-(sulfo)-D-myo-inositol 1,4-O-bis(dibenzyl phosphate)

There total 5 articles about (-)-2,3,6-tri-O-benzyl-5-O-(sulfo)-D-myo-inositol 1,4-O-bis(dibenzyl phosphate) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 52.0%

: 145842-31-5
(+)-2,3,6-tri-O-benzyl-D-myo-inositol 1,4-O-bis(dibenzyl phosphate)

: 1262331-30-5
(-)-2,3,6-tri-O-benzyl-5-O-(sulfo)-D-myo-inositol 1,4-O-bis(dibenzyl phosphate)

Guidance literature:: With sulfur trioxide pyridine complex; In N,N-dimethyl-formamide; at 50 ℃; for 16h; Inert atmosphere;
DOI:10.1039/c0cc03003a

Reference yield:

: 1262487-25-1
(-)-5-O-allyl-2,3,6-tris-O-benzyl-D-myo-inositol

: 1262331-30-5
(-)-2,3,6-tri-O-benzyl-5-O-(sulfo)-D-myo-inositol 1,4-O-bis(dibenzyl phosphate)

Guidance literature:: Multi-step reaction with 4 steps

1.1: 1H-tetrazole / dichloromethane; acetonitrile / 0.25 h / Inert atmosphere

1.2: 16 h / 20 °C / Inert atmosphere

2.1: 3-chloro-benzenecarboperoxoic acid / dichloromethane; acetonitrile / 1.83 h / -78 - 20 °C / Inert atmosphere

3.1: methanol; palladium dichloride / 2.5 h / 20 °C / Inert atmosphere

3.2: 0.25 h

4.1: sulfur trioxide pyridine complex / N,N-dimethyl-formamide / 16 h / 50 °C / Inert atmosphere

With 1H-tetrazole; methanol; sulfur trioxide pyridine complex; 3-chloro-benzenecarboperoxoic acid; palladium dichloride; In dichloromethane; N,N-dimethyl-formamide; acetonitrile;
DOI:10.1039/c0cc03003a

Reference yield:

: 196302-92-8
1D-5-O-allyl-2,6-di-O-benzyl-3-O-endo,4-O-exo-(L-1',7',7'-trimethylbicyclo<2.2.1>hept-2'-ylidene)-myo-inositol

: 1262331-30-5
(-)-2,3,6-tri-O-benzyl-5-O-(sulfo)-D-myo-inositol 1,4-O-bis(dibenzyl phosphate)

Guidance literature:: Multi-step reaction with 6 steps

1.1: methanol; acetyl chloride / dichloromethane / 18 h / 20 °C / Inert atmosphere

2.1: tetrabutylammomium bromide; di(n-butyl)tin oxide / acetonitrile / 20 h / Inert atmosphere; Reflux

3.1: 1H-tetrazole / dichloromethane; acetonitrile / 0.25 h / Inert atmosphere

3.2: 16 h / 20 °C / Inert atmosphere

4.1: 3-chloro-benzenecarboperoxoic acid / dichloromethane; acetonitrile / 1.83 h / -78 - 20 °C / Inert atmosphere

5.1: methanol; palladium dichloride / 2.5 h / 20 °C / Inert atmosphere

5.2: 0.25 h

6.1: sulfur trioxide pyridine complex / N,N-dimethyl-formamide / 16 h / 50 °C / Inert atmosphere

With 1H-tetrazole; methanol; tetrabutylammomium bromide; sulfur trioxide pyridine complex; di(n-butyl)tin oxide; acetyl chloride; 3-chloro-benzenecarboperoxoic acid; palladium dichloride; In dichloromethane; N,N-dimethyl-formamide; acetonitrile;
DOI:10.1039/c0cc03003a