4-(2',2'-dimethyl-6'-methylidenecyclohexyl)butanal

Base Information

Chemical Name:4-(2',2'-dimethyl-6'-methylidenecyclohexyl)butanal
CAS No.:95452-13-4
Molecular Formula:C₁₃H₂₂O
Molecular Weight:194.317
Hs Code.:

Synonyms:4-(2',2'-dimethyl-6'-methylidenecyclohexyl)butanal

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Chemical Property of 4-(2',2'-dimethyl-6'-methylidenecyclohexyl)butanal

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Technology Process of 4-(2',2'-dimethyl-6'-methylidenecyclohexyl)butanal

There total 9 articles about 4-(2',2'-dimethyl-6'-methylidenecyclohexyl)butanal which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 50.0%

: 95452-12-3
4-(2',2'-dimethyl-6'-methylidenecyclohexyl)butanal-bis<(tert-butyl)dimethylsilyl>-acetal

: 95452-13-4
4-(2',2'-dimethyl-6'-methylidenecyclohexyl)butanal

Guidance literature:: With hydrogenchloride; In diethyl ether; water; for 72h; Ambient temperature;
DOI:10.1002/hlca.19840670711

Reference yield: 16.0%

: 95452-00-9
4-(2',2'-dimethyl-6'-methylenecyclohexyl)-1-<(tert-butyl)dimethylsilyl>-1-butanone

: 2-ethenyl-1,1-dimethyl-3-methylene-cyclohexane

: 95452-13-4
4-(2',2'-dimethyl-6'-methylidenecyclohexyl)butanal

: 3-<(tert-butyl)dimethylsilyloxy>-8,8-dimethyltricyclo<5.4.0.0^1,3>undecane

: 95452-12-3
4-(2',2'-dimethyl-6'-methylidenecyclohexyl)butanal-bis<(tert-butyl)dimethylsilyl>-acetal

: 556076-23-4
2-<(tert-butyl)dimethylsilyl>-4-<(tert-butyl)dimethylsilyloxy>-7-(2',2'-dimethyl-6'-mthylidenecyclohexyl)-3-oxa-1-heptene

: (Z)-1-<(tert-butyl)dimethylsilyloxy>-4-(2',2'-dimethylidenecyclohexyl)-1-butene

Guidance literature:: In acetonitrile; Product distribution; Irradiation; investigation of the photolyses of the acylsilane;
DOI:10.1002/hlca.19840670711

Reference yield:

: 13720-12-2
4-(2',2'-Dimethyl-6'-methylidenecyclohexyl)butan-2-one

: 95452-13-4
4-(2',2'-dimethyl-6'-methylidenecyclohexyl)butanal

Guidance literature:: Multi-step reaction with 8 steps

1: 1) I₂, 2) 2N NaOH / 1) pyridine, 100 deg C, 1 h; 2) 100 deg C, overnight

2: 88 percent / LiAlH₄ / diethyl ether / 2 h / Ambient temperature

3: 81 percent / pyridine / 0.08 h / Ambient temperature

4: 96 percent / NaI / 1,2-dimethoxy-ethane / 18 h / 50 °C

5: 92 percent / BuLi / tetrahydrofuran; hexamethylphosphoric acid triamide; hexane / 2.5 h / Ambient temperature

6: 54 percent / Tl(NO₃)3*3H₂O / tetrahydrofuran; H₂O; methanol / 0.08 h / Ambient temperature

7: 61 percent / (tert-butyl)dimethylsilanol / acetonitrile / Irradiation

8: 50 percent / 10percent HCl / diethyl ether; H₂O / 72 h / Ambient temperature

With pyridine; hydrogenchloride; sodium hydroxide; lithium aluminium tetrahydride; n-butyllithium; tert-butyldimethylsilanol; iodine; thallium(III) nitrate; sodium iodide; In tetrahydrofuran; methanol; N,N,N,N,N,N-hexamethylphosphoric triamide; 1,2-dimethoxyethane; diethyl ether; hexane; water; acetonitrile;
DOI:10.1002/hlca.19840670711