tris(styrene)platinum⁽⁰⁾

Base Information

• Chemical Name: tris(styrene)platinum⁽⁰⁾
• CAS No.: 113948-64-4
• Molecular Formula: C₂₄H₂₄Pt
• Molecular Weight: 507.535
• Mol file: 113948-64-4.mol

Synonyms:tris(styrene)platinum⁽⁰⁾

Chemical Property of tris(styrene)platinum⁽⁰⁾

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of tris(styrene)platinum⁽⁰⁾

There total 3 articles about tris(styrene)platinum⁽⁰⁾ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

styrene (100-42-5,25038-60-2,25247-68-1,28213-80-1,28325-75-9,79637-11-9,9003-53-6) + cis-dichlorobis(η(2)styrene)platinum(II) (106862-48-0,59982-22-8,106862-50-4,70878-43-2,106862-49-1,344358-05-0) → Pt(PhCHCH2)3 (113948-64-4)

Guidance literature:

With HSiPh₃; In further solvent(s); Stirring for 30 min yields a yellow soln.; (195)Pt-NMR., stirring of the styrene soln. with H2O and conc. aq. NH3 for 75 min, sepg., stirring with additionyl H2O for 20 min, sepg., column chromy. (Al2O3, styrene).;

Reference yield:

cis-dichlorobis(η(2)styrene)platinum(II) (106862-48-0,59982-22-8,106862-50-4,70878-43-2,106862-49-1,344358-05-0) → tris(styrene)platinum(0) (113948-64-4)

Guidance literature:

With HSiPh₃; In further solvent(s); byproducts: Ph3SiCl; further solvent: styrene, Ph3SiCl removed by passagebthe solution through column of basic alumina; W.R. Cesari and P.S. Pregosin, Organometallics, in press; NMR;

DOI:10.1016/0022-328X(88)83096-1

Reference yield:

PtBr2(C6H5CHCH2)2 → Pt(PhCHCH2)3 (113948-64-4)

Guidance literature:

upstream raw materials:

styrene

cis-dichlorobis(η(2)styrene)platinum(II)

Downstream raw materials:

bis(diphenylacetylene)platinum⁽⁰⁾

bis(O,O'-diethyldithiophosphato-S,S')platinum(II)

platinum

[platinum⁽⁰⁾bis(1,2-bis(diphenylphosphino)ethane)]

Refernces

• 1、 Caseri,Pregosin. "HYDROSILYLATION CHEMISTRY AND CATALYSIS WITH cis-PtCl2(PhCH equals CH2)2.". . p. 1373 - 1380. Retrieved 2008/10/08.