Technology Process of <13-(3-Pyridyl)tridecyl>-p-toluolsulfonat
There total 7 articles about <13-(3-Pyridyl)tridecyl>-p-toluolsulfonat which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
With
pyridine;
at 0 ℃;
for 1h;
- Guidance literature:
-
Multi-step reaction with 5 steps
1: 1) Mg, Dibromethan / 1) Et2O/THF, 2) THF, 4 h
2: 1) DMSO/oxalylchlorid, 2) NEt3 / 1) CH2Cl2, -50 deg C, 1 h, 2) -50 deg C to 0 deg C
3: 1) Hydrazin-Hydrat, 2) 85percent KOH / 1) EtOH/diethylenglycol, reflux, 4 h, 2) 200 deg C, 7 h
4: 97 percent / H2 / 5percent Pd/C / acetic acid / 3 h / 750.06 Torr
5: 100 percent / Pyridin / 1 h / 0 °C
With
pyridine; potassium hydroxide; oxalyl dichloride; 1,1-Dibromoethane; hydrogen; hydrazine hydrate; magnesium; dimethyl sulfoxide; triethylamine;
palladium on activated charcoal;
In
acetic acid;
- Guidance literature:
-
Multi-step reaction with 6 steps
1: 60 percent / 33percent aq. NaOH / nBu4NHSO4 / 27 h / 35 °C
2: 1) Mg, Dibromethan / 1) Et2O/THF, 2) THF, 4 h
3: 1) DMSO/oxalylchlorid, 2) NEt3 / 1) CH2Cl2, -50 deg C, 1 h, 2) -50 deg C to 0 deg C
4: 1) Hydrazin-Hydrat, 2) 85percent KOH / 1) EtOH/diethylenglycol, reflux, 4 h, 2) 200 deg C, 7 h
5: 97 percent / H2 / 5percent Pd/C / acetic acid / 3 h / 750.06 Torr
6: 100 percent / Pyridin / 1 h / 0 °C
With
pyridine; potassium hydroxide; sodium hydroxide; oxalyl dichloride; 1,1-Dibromoethane; hydrogen; hydrazine hydrate; magnesium; dimethyl sulfoxide; triethylamine;
palladium on activated charcoal; tetra(n-butyl)ammonium hydrogensulfate;
In
acetic acid;
