N,N'-bis{4-[2-(triisopropylsilanyl)ethynylphenyl]}-2-chloro-6-(3,5-di-tert-butylbenzylamine)-1,4,5,8-tetracarboxylic acid naphthalenediimide

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Chemical Name:N,N'-bis{4-[2-(triisopropylsilanyl)ethynylphenyl]}-2-chloro-6-(3,5-di-tert-butylbenzylamine)-1,4,5,8-tetracarboxylic acid naphthalenediimide
CAS No.:1266490-64-5
Molecular Formula:C₆₃H₇₆ClN₃O₄Si₂
Molecular Weight:1030.94
Hs Code.:

Synonyms:N,N'-bis{4-[2-(triisopropylsilanyl)ethynylphenyl]}-2-chloro-6-(3,5-di-tert-butylbenzylamine)-1,4,5,8-tetracarboxylic acid naphthalenediimide

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Chemical Property of N,N'-bis{4-[2-(triisopropylsilanyl)ethynylphenyl]}-2-chloro-6-(3,5-di-tert-butylbenzylamine)-1,4,5,8-tetracarboxylic acid naphthalenediimide

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Technology Process of N,N'-bis{4-[2-(triisopropylsilanyl)ethynylphenyl]}-2-chloro-6-(3,5-di-tert-butylbenzylamine)-1,4,5,8-tetracarboxylic acid naphthalenediimide

There total 6 articles about N,N'-bis{4-[2-(triisopropylsilanyl)ethynylphenyl]}-2-chloro-6-(3,5-di-tert-butylbenzylamine)-1,4,5,8-tetracarboxylic acid naphthalenediimide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 54.0%

: 1266490-63-4
N,N'-bis{4-[2-(triisopropylsilanyl)ethynylphenyl]}-2,6-dichloro-1,4,5,8-tetracarboxylic acid naphthalenediimide

: 139693-30-4
(3,5-di-tert-butyl)benzylamine

: 1266490-64-5
N,N'-bis{4-[2-(triisopropylsilanyl)ethynylphenyl]}-2-chloro-6-(3,5-di-tert-butylbenzylamine)-1,4,5,8-tetracarboxylic acid naphthalenediimide

Guidance literature:: With potassium carbonate; In N,N-dimethyl-formamide; at 40 ℃; for 8.5h; Inert atmosphere;
DOI:10.1002/ejoc.201001415

Reference yield:

: 62938-08-3
3,5-di-tert-butylbenzyl bromide

: 1266490-64-5
N,N'-bis{4-[2-(triisopropylsilanyl)ethynylphenyl]}-2-chloro-6-(3,5-di-tert-butylbenzylamine)-1,4,5,8-tetracarboxylic acid naphthalenediimide

Guidance literature:: Multi-step reaction with 3 steps

1: potassium carbonate / N,N-dimethyl-formamide / 24 h / 25 °C / Inert atmosphere

2: hydrazine / tetrahydrofuran / 3 h / 70 °C / Inert atmosphere

3: potassium carbonate / N,N-dimethyl-formamide / 8.5 h / 40 °C / Inert atmosphere

With potassium carbonate; hydrazine; In tetrahydrofuran; N,N-dimethyl-formamide;
DOI:10.1002/ejoc.201001415

Reference yield:

: 89343-06-6
tris-iso-propylsilyl acetylene

: 1266490-64-5
N,N'-bis{4-[2-(triisopropylsilanyl)ethynylphenyl]}-2-chloro-6-(3,5-di-tert-butylbenzylamine)-1,4,5,8-tetracarboxylic acid naphthalenediimide

Guidance literature:: Multi-step reaction with 3 steps

1: copper(l) iodide; bis-triphenylphosphine-palladium(II) chloride; triethylamine / tetrahydrofuran / 5 h / 25 °C / Inert atmosphere

2: acetic anhydride / 0.5 h / 120 °C / Inert atmosphere

3: potassium carbonate / N,N-dimethyl-formamide / 8.5 h / 40 °C / Inert atmosphere

With bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; acetic anhydride; potassium carbonate; triethylamine; In tetrahydrofuran; N,N-dimethyl-formamide; 1: Sonogashira coupling;
DOI:10.1002/ejoc.201001415