[Ni(N,N'-diethyl-3,7-diazanonane-1,9-dithiolate)Pd(SCH₂CH₂PPh₂)][PF₆]

Base Information

• Chemical Name: [Ni(N,N'-diethyl-3,7-diazanonane-1,9-dithiolate)Pd(SCH₂CH₂PPh₂)][PF₆]
• CAS No.: 847830-75-5
• Molecular Formula: C₂₅H₃₈N₂NiPPdS₃*F₆P
• Molecular Weight: 803.836

Synonyms:[Ni(N,N'-diethyl-3,7-diazanonane-1,9-dithiolate)Pd(SCH₂CH₂PPh₂)][PF₆]

Chemical Property of [Ni(N,N'-diethyl-3,7-diazanonane-1,9-dithiolate)Pd(SCH₂CH₂PPh₂)][PF₆]

Chemical Property:

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Technology Process of [Ni(N,N'-diethyl-3,7-diazanonane-1,9-dithiolate)Pd(SCH₂CH₂PPh₂)][PF₆]

There total 1 articles about [Ni(N,N'-diethyl-3,7-diazanonane-1,9-dithiolate)Pd(SCH₂CH₂PPh₂)][PF₆] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

sodium hexaflorophosphate + [N,N'-diethyl-3,7-diazanonane-1,9-dithiolato]nickel(II) (176445-58-2) + [Pd(SCH2CH2PPh2)(PPh3)Cl] (247938-85-8,847907-92-0,247221-19-8) → [Ni(N,N'-diethyl-3,7-diazanonane-1,9-dithiolate)Pd(SCH2CH2PPh2)][PF6] (847830-75-5)

Guidance literature:

In acetonitrile; under pure N2 atm.; to soln. of Ni(N,N'-diethyl-3,7-diazanonane-1,9-dithiolate) in MeCN added suspn. of Pd(SCH2CH2PPh2)Cl(PPh3) in MeCN; suspn. of NaPF6 in MeCN added; soln. stirred for 3 h; mixt. filtered through Celite; filtrate concd.; ether was diffused into filtrate; elem. anal.;

DOI:10.1021/ja040222n

Reference yield:

[Ni(N,N'-diethyl-3,7-diazanonane-1,9-dithiolate)Pd(SCH2CH2PPh2)][PF6] (847830-75-5) + [Bu4N]2[Fe4S4(1,3,5-tris((4,6-dimethyl-3-mercaptophenyl)thio)-2,4,6-tris(p-tolylthio)benzene(3-))(triflate)] → [Bu4N][Fe4S4(1,3,5-tris((4,6-dimethyl-3-mercaptophenyl)thio)-2,4,6-tris(p-tolylthio)benzene(3-))Ni(N,N'-diethyl-3,7-diazanonane-1,9-dithiolate)]

Guidance literature:

In dichloromethane-d2; byproducts: CF3SO3(1-); monitored by NMR-spectroscopy;

DOI:10.1021/ja040222n

upstream raw materials:

[N,N'-diethyl-3,7-diazanonane-1,9-dithiolato]nickel(II)

[Pd(SCH₂CH₂PPh₂)(PPh₃)Cl]

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