Technology Process of C26H25ClO4
There total 3 articles about C26H25ClO4 which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
With
N-((2S,3S)-1-(diphenylphosphino)-3-methylpentan-2-yl)-3,5-bis(trifluoromethyl)benzamide;
In
toluene;
at 20 ℃;
for 12h;
Reagent/catalyst;
enantioselective reaction;
DOI:10.1002/anie.201302045
- Guidance literature:
-
Multi-step reaction with 3 steps
1: tributylphosphine; phenol / tetrahydrofuran / 12 h / 20 °C
2: Dess-Martin periodane / dichloromethane / 20 °C
3: N-((2S,3S)-1-(diphenylphosphino)-3-methylpentan-2-yl)-3,5-bis(trifluoromethyl)benzamide / toluene / 12 h / 20 °C
With
tributylphosphine; N-((2S,3S)-1-(diphenylphosphino)-3-methylpentan-2-yl)-3,5-bis(trifluoromethyl)benzamide; Dess-Martin periodane; phenol;
In
tetrahydrofuran; dichloromethane; toluene;
2: |Dess-Martin Oxidation;
DOI:10.1002/anie.201302045
- Guidance literature:
-
Multi-step reaction with 2 steps
1: Dess-Martin periodane / dichloromethane / 20 °C
2: N-((2S,3S)-1-(diphenylphosphino)-3-methylpentan-2-yl)-3,5-bis(trifluoromethyl)benzamide / toluene / 12 h / 20 °C
With
N-((2S,3S)-1-(diphenylphosphino)-3-methylpentan-2-yl)-3,5-bis(trifluoromethyl)benzamide; Dess-Martin periodane;
In
dichloromethane; toluene;
1: |Dess-Martin Oxidation;
DOI:10.1002/anie.201302045