Technology Process of C22H38O5Si
There total 13 articles about C22H38O5Si which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
With
dmap; triethylamine;
In
dichloromethane;
at 0 - 20 ℃;
DOI:10.1021/ol070405p
- Guidance literature:
-
Multi-step reaction with 6 steps
1: LiAlH4 / CH2Cl2 / 1 h / -78 °C
2: 86 percent / i-BuMgBr / Cp2TiCl2 / diethyl ether / 0 - 20 °C
3: NaHCO3; m-CPBA / CH2Cl2 / 20 h / -4 °C
4: 98 percent / Dess-Martin periodinane / CH2Cl2 / 8.5 h / 0 - 20 °C
5: 65 percent / SmI2 / tetrahydrofuran / 1.33 h / -90 - -78 °C
6: 75 percent / Et3N; DMAP / CH2Cl2 / 0 - 20 °C
With
dmap; lithium aluminium tetrahydride; samarium diiodide; isobutylmagnesium bromide; sodium hydrogencarbonate; Dess-Martin periodane; triethylamine; 3-chloro-benzenecarboperoxoic acid;
bis(cyclopentadienyl)titanium dichloride;
In
tetrahydrofuran; diethyl ether; dichloromethane;
DOI:10.1021/ol070405p
- Guidance literature:
-
Multi-step reaction with 5 steps
1: 86 percent / i-BuMgBr / Cp2TiCl2 / diethyl ether / 0 - 20 °C
2: NaHCO3; m-CPBA / CH2Cl2 / 20 h / -4 °C
3: 98 percent / Dess-Martin periodinane / CH2Cl2 / 8.5 h / 0 - 20 °C
4: 65 percent / SmI2 / tetrahydrofuran / 1.33 h / -90 - -78 °C
5: 75 percent / Et3N; DMAP / CH2Cl2 / 0 - 20 °C
With
dmap; samarium diiodide; isobutylmagnesium bromide; sodium hydrogencarbonate; Dess-Martin periodane; triethylamine; 3-chloro-benzenecarboperoxoic acid;
bis(cyclopentadienyl)titanium dichloride;
In
tetrahydrofuran; diethyl ether; dichloromethane;
DOI:10.1021/ol070405p
