[(2R)-2-(2-hydroxy-3-tosyloxy)propyl] 2-O-benzyl-3,4-di-O-benzoyl-α-D-xylopyranoside

Base Information

Chemical Name:[(2R)-2-(2-hydroxy-3-tosyloxy)propyl] 2-O-benzyl-3,4-di-O-benzoyl-α-D-xylopyranoside
CAS No.:418766-85-5
Molecular Formula:C₃₆H₃₆O₁₁S
Molecular Weight:676.741
Hs Code.:

Synonyms:[(2R)-2-(2-hydroxy-3-tosyloxy)propyl] 2-O-benzyl-3,4-di-O-benzoyl-α-D-xylopyranoside

Suppliers and Price of [(2R)-2-(2-hydroxy-3-tosyloxy)propyl] 2-O-benzyl-3,4-di-O-benzoyl-α-D-xylopyranoside

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of [(2R)-2-(2-hydroxy-3-tosyloxy)propyl] 2-O-benzyl-3,4-di-O-benzoyl-α-D-xylopyranoside

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of [(2R)-2-(2-hydroxy-3-tosyloxy)propyl] 2-O-benzyl-3,4-di-O-benzoyl-α-D-xylopyranoside

There total 2 articles about [(2R)-2-(2-hydroxy-3-tosyloxy)propyl] 2-O-benzyl-3,4-di-O-benzoyl-α-D-xylopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 73.0%

: 98-59-9
p-toluenesulfonyl chloride

: 270580-83-1
C₂₉H₃₀O₉

: 418766-85-5
[(2R)-2-(2-hydroxy-3-tosyloxy)propyl] 2-O-benzyl-3,4-di-O-benzoyl-α-D-xylopyranoside

Guidance literature:: In pyridine; at 20 ℃; for 2h;
DOI:10.1016/S0968-0896(01)00329-7

Reference yield:

: 196859-39-9
allyl 3,4-di-O-benzoyl-2-O-benzyl-α-D-xylopyranoside

: 418766-85-5
[(2R)-2-(2-hydroxy-3-tosyloxy)propyl] 2-O-benzyl-3,4-di-O-benzoyl-α-D-xylopyranoside

Guidance literature:: Multi-step reaction with 2 steps

1: AD-mix β; PYR(DHQD)2 / 2-methyl-propan-2-ol; H2O

2: 73 percent / pyridine / 2 h / 20 °C

With hydroquinindine-2,5-diphenyl-4,6-pyrimidinediyl diether; 1,4-bis(9-O-dihydroquinidine)phthalazine; In pyridine; water; tert-butyl alcohol; 1: Sharpless dihydroxylation;
DOI:10.1016/S0968-0896(01)00329-7

Reference yield: 63.0%

: 66224-66-6,66224-67-7,66224-68-8,66224-69-9,134434-48-3,134434-49-4,134454-76-5,134461-75-9
adenine

: 418766-85-5
[(2R)-2-(2-hydroxy-3-tosyloxy)propyl] 2-O-benzyl-3,4-di-O-benzoyl-α-D-xylopyranoside

: 418766-87-7
[(2R)-[2-hydroxy-3-(6-amino-9H-purin-9-yl)]propyl] 2-O-benzyl-3,4-di-O-benzoyl-α-D-xylopyranoside

: [(2R)-[2-hydroxy-3-(6-amino-7H-purin-7-yl)]propyl] 2-O-benzyl-3,4-di-O-benzoyl-α-D-xylopyranoside

Guidance literature:: adenine; With sodium hydride; In N,N-dimethyl-formamide; at 80 ℃; for 1.5h;

[(2R)-2-(2-hydroxy-3-tosyloxy)propyl] 2-O-benzyl-3,4-di-O-benzoyl-α-D-xylopyranoside; In N,N-dimethyl-formamide; at 80 ℃; for 3h;
DOI:10.1016/S0968-0896(01)00329-7