(Z)-5-(tert-butyldiphenylsilyloxy)-2-methylpent-2-enyl methyl carbonate

Base Information

Chemical Name:(Z)-5-(tert-butyldiphenylsilyloxy)-2-methylpent-2-enyl methyl carbonate
CAS No.:1350729-92-8
Molecular Formula:C₂₄H₃₂O₄Si
Molecular Weight:412.601
Hs Code.:

Synonyms:(Z)-5-(tert-butyldiphenylsilyloxy)-2-methylpent-2-enyl methyl carbonate

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Chemical Property of (Z)-5-(tert-butyldiphenylsilyloxy)-2-methylpent-2-enyl methyl carbonate

Chemical Property:

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Technology Process of (Z)-5-(tert-butyldiphenylsilyloxy)-2-methylpent-2-enyl methyl carbonate

There total 3 articles about (Z)-5-(tert-butyldiphenylsilyloxy)-2-methylpent-2-enyl methyl carbonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 82.0%

: 79-22-1
methyl chloroformate

: (Z)-5-(tert-butyldiphenylsilyloxy)-2-methylpent-2-en-1-ol

: 1350729-92-8
(Z)-5-(tert-butyldiphenylsilyloxy)-2-methylpent-2-enyl methyl carbonate

Guidance literature:: With pyridine; In dichloromethane; at 0 ℃; for 1h; Inert atmosphere;
DOI:10.1039/c1ob06619f

Reference yield:

: 1350729-90-6
(Z)-ethyl 5-(tert-butyldiphenylsilyloxy)-2-methylpent-2-enoate

: 1350729-92-8
(Z)-5-(tert-butyldiphenylsilyloxy)-2-methylpent-2-enyl methyl carbonate

Guidance literature:: Multi-step reaction with 2 steps

1: diisobutylaluminium hydride / toluene / 2 h / -78 - 20 °C / Inert atmosphere

2: pyridine / dichloromethane / 1 h / 0 °C / Inert atmosphere

With pyridine; diisobutylaluminium hydride; In dichloromethane; toluene;
DOI:10.1039/c1ob06619f

Reference yield:

: 112897-03-7
3-(tert-butyldiphenylsilyloxy)-1-propanal

: 1350729-92-8
(Z)-5-(tert-butyldiphenylsilyloxy)-2-methylpent-2-enyl methyl carbonate

Guidance literature:: Multi-step reaction with 3 steps

1.1: 1,8-diazabicyclo[5.4.0]undec-7-ene; sodium iodide / tetrahydrofuran / 0.17 h / 0 °C / Inert atmosphere

1.2: 2.17 h / -78 - 20 °C / Inert atmosphere

2.1: diisobutylaluminium hydride / toluene / 2 h / -78 - 20 °C / Inert atmosphere

3.1: pyridine / dichloromethane / 1 h / 0 °C / Inert atmosphere

With pyridine; diisobutylaluminium hydride; 1,8-diazabicyclo[5.4.0]undec-7-ene; sodium iodide; In tetrahydrofuran; dichloromethane; toluene; 1.1: Horner-Wadsworth-Emmons reaction / 1.2: Horner-Wadsworth-Emmons reaction;
DOI:10.1039/c1ob06619f