CpCr[((2,6-diethylphenyl)NCMe)2CH](Cl)

Base Information

• Chemical Name: CpCr[((2,6-diethylphenyl)NCMe)2CH](Cl)
• CAS No.: 1198298-24-6
• Molecular Formula: C₃₀H₃₈ClCrN₂
• Molecular Weight: 514.094
• Mol file: 1198298-24-6.mol

Synonyms:CpCr[((2,6-diethylphenyl)NCMe)2CH](Cl)

Chemical Property of CpCr[((2,6-diethylphenyl)NCMe)2CH](Cl)

Chemical Property:

Purity/Quality:

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Technology Process of CpCr[((2,6-diethylphenyl)NCMe)2CH](Cl)

There total 1 articles about CpCr[((2,6-diethylphenyl)NCMe)2CH](Cl) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 79.4%

(2,6-diethylphenyl)NHC(CH3)CHC(CH3)N(2,6-diethylphenyl) + chromium(III) chloride (10025-73-7,16284-59-6) + sodium cyclopentadienide → CpCr[((2,6-diethylphenyl)NCMe)2CH](Cl) (1198298-24-6)

Guidance literature:

With n-BuLi; In tetrahydrofuran; hexane; under N2; n-BuLi in hexanes added dropwise with stirring to soln. of ligand in THF (0°C); warmed to room temp. (40 min); added to suspn. of CrCl3 in THF; stirred at room temp. overnight; NaC5H5 in THF added; stirred at room temp. overnight; solvent removed in vac.; extd. with hexanes, Et2O and CH2Cl2; filtered through Celite; rinsed with hexanes; concd.; cooled to -20°C; crystals isolated in three crops over several d; elem. anal.;

DOI:10.1021/om900788c

upstream raw materials:

chromium(III) chloride