4,4,7-trimethyl-6-methylene-3,4,5,6-tetrahydro-2H-azepin-1-ium diphenyl phosphate

Base Information

Chemical Name:4,4,7-trimethyl-6-methylene-3,4,5,6-tetrahydro-2H-azepin-1-ium diphenyl phosphate
CAS No.:1312472-57-3
Molecular Formula:C₁₀H₁₇N*C₁₂H₁₁O₄P
Molecular Weight:401.442
Hs Code.:

Synonyms:4,4,7-trimethyl-6-methylene-3,4,5,6-tetrahydro-2H-azepin-1-ium diphenyl phosphate

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Chemical Property of 4,4,7-trimethyl-6-methylene-3,4,5,6-tetrahydro-2H-azepin-1-ium diphenyl phosphate

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Technology Process of 4,4,7-trimethyl-6-methylene-3,4,5,6-tetrahydro-2H-azepin-1-ium diphenyl phosphate

There total 8 articles about 4,4,7-trimethyl-6-methylene-3,4,5,6-tetrahydro-2H-azepin-1-ium diphenyl phosphate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

: 838-85-7
diphenyl hydrogen phosphate

: 1312472-56-2
4,4,7-trimethyl-6-methylene-3,4,5,6-tetrahydro-2H-azepin-1-ium trifluoroacetate

: 1312472-57-3
4,4,7-trimethyl-6-methylene-3,4,5,6-tetrahydro-2H-azepin-1-ium diphenyl phosphate

Guidance literature:: In methanol;
DOI:10.1021/ol201448h

Reference yield:

: 1312472-81-3
tert-butyl (5-((dimethylamino)methyl)-6-(methoxy(methyl)amino)-3,3-dimethyl-6-oxohexyl)carbamate

: 1312472-57-3
4,4,7-trimethyl-6-methylene-3,4,5,6-tetrahydro-2H-azepin-1-ium diphenyl phosphate

Guidance literature:: Multi-step reaction with 4 steps

1.1: tetrahydrofuran; diethyl ether / 1 h / -78 °C / Inert atmosphere

2.1: 3-chloro-benzenecarboperoxoic acid / dichloromethane / 15 h / 20 °C / Inert atmosphere

3.1: trifluoroacetic acid / dichloromethane / 0.5 h / 20 °C / Inert atmosphere

3.2: 0.75 h / Inert atmosphere; Reflux

4.1: methanol

With 3-chloro-benzenecarboperoxoic acid; trifluoroacetic acid; In tetrahydrofuran; methanol; diethyl ether; dichloromethane;
DOI:10.1021/ol201448h

Reference yield:

: 1312472-80-2
tert-butyl 3-((dimethylamino)methyl)-5,5-dimethyl-2-oxoazepane-1-carboxylate

: 1312472-57-3
4,4,7-trimethyl-6-methylene-3,4,5,6-tetrahydro-2H-azepin-1-ium diphenyl phosphate

Guidance literature:: Multi-step reaction with 5 steps

1.1: trimethylaluminum / dichloromethane; toluene / 0 - 20 °C / Inert atmosphere

1.2: 2 h / 0 - 20 °C / Inert atmosphere

2.1: tetrahydrofuran; diethyl ether / 1 h / -78 °C / Inert atmosphere

3.1: 3-chloro-benzenecarboperoxoic acid / dichloromethane / 15 h / 20 °C / Inert atmosphere

4.1: trifluoroacetic acid / dichloromethane / 0.5 h / 20 °C / Inert atmosphere

4.2: 0.75 h / Inert atmosphere; Reflux

5.1: methanol

With trimethylaluminum; 3-chloro-benzenecarboperoxoic acid; trifluoroacetic acid; In tetrahydrofuran; methanol; diethyl ether; dichloromethane; toluene;
DOI:10.1021/ol201448h