12-Ph₃P-closo-1-CB₁₁H₁₁

Base Information

• Chemical Name: 12-Ph₃P-closo-1-CB₁₁H₁₁
• CAS No.: 1356112-39-4
• Molecular Formula: C₁₉H₂₆B₁₁P
• Molecular Weight: 404.31
• Mol file: 1356112-39-4.mol

Synonyms:12-Ph₃P-closo-1-CB₁₁H₁₁

Chemical Property of 12-Ph₃P-closo-1-CB₁₁H₁₁

Chemical Property:

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Technology Process of 12-Ph₃P-closo-1-CB₁₁H₁₁

There total 1 articles about 12-Ph₃P-closo-1-CB₁₁H₁₁ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

Cs[12-I-carba-closo-dodecaborate] + triphenylphosphine (603-35-0) → 12-Ph3P-closo-1-CB11H11 (1356112-39-4)

Guidance literature:

With K₂CO₃; tetrakis(triphenylphosphine) palladium⁽⁰⁾; In tetrahydrofuran; other Radiation; under Ar dodecaborate, Pd(PPh3)4, PPh3 and K2CO3 dissolved in THF, heated to 66°C by microwave irradiation for 4 h; THF removed (reduced pressure), residue dissolved in chloroform, pptn. by hexane addn.; elem. anal.;

DOI:10.1021/ic202638k

upstream raw materials:

triphenylphosphine