trans-PtCl(C₆F₅)(PPh₂(CH₂)2C(CH₃)2(CH₂)3CH=CH₂)2

Base Information

• Chemical Name: trans-PtCl(C₆F₅)(PPh₂(CH₂)2C(CH₃)2(CH₂)3CH=CH₂)2
• CAS No.: 647012-12-2
• Molecular Formula: C₅₀H₅₈ClF₅P₂Pt
• Molecular Weight: 1046.48
• Mol file: 647012-12-2.mol

Synonyms:trans-PtCl(C₆F₅)(PPh₂(CH₂)2C(CH₃)2(CH₂)3CH=CH₂)2

Chemical Property of trans-PtCl(C₆F₅)(PPh₂(CH₂)2C(CH₃)2(CH₂)3CH=CH₂)2

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of trans-PtCl(C₆F₅)(PPh₂(CH₂)2C(CH₃)2(CH₂)3CH=CH₂)2

There total 1 articles about trans-PtCl(C₆F₅)(PPh₂(CH₂)2C(CH₃)2(CH₂)3CH=CH₂)2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 63.0%

{platinum(II)(μ-chloride)(pentafluorophenyl)(tetrahydrothiophene)}2 + (C6H5)2P(CH2)2C(CH3)2(CH2)3CHCH2 (647012-08-6) → trans-PtCl(C6F5)(PPh2(CH2)2C(CH3)2(CH2)3CH=CH2)2 (647012-12-2)

Guidance literature:

In dichloromethane; under N2; mixt. of (Pt(μ-Cl)(C6F5)(SC4H8))2 and phosphane in CH2Cl2 was stirred for 16 h; solvent removed in vacuo, chromy. (neutral alumina, CH2Cl2/hexane (1/2)), evapd. in vacuo; elem. anal.;

DOI:10.1021/om034121u

Reference yield: 86.0%

Butadiyne (460-12-8,27987-87-7) + trans-PtCl(C6F5)(PPh2(CH2)2C(CH3)2(CH2)3CH=CH2)2 (647012-12-2) → trans-(C6F5)(Ph2P(CH2)2C(CH3)2(CH2)3CH=CH2)2Pt(CC)2H (952610-21-8)

Guidance literature:

With HNEt₂; copper(l) iodide; In tetrahydrofuran; dichloromethane; a Schlenk flask was charged with Pt-contg. compd. (0.323 mmol), CuI (0.065 mmol), CH2Cl2, and HNEt2, and cooled to -45°C; then H(CC)2H (5.17 mmol) in THF was added with stirring; cold bath was allowed to warm to 10°C for 3 h and removed; after an addnl. 2.5 h (orange supernatant/white ppt.), the solvent was removed by oil pump vac.; the residue was extd. with toluene; combined exts. were filtered through alumina column (toluene rinses); solvent was removed by oil pump vac.; elem. anal.;

Reference yield:

trans-PtCl(C6F5)(PPh2(CH2)2C(CH3)2(CH2)3CH=CH2)2 (647012-12-2) → trans-PtCl(C6F5)(PPh2(CH2)2C(CH3)2(CH2)8C(CH3)2(CH2)2PPh2) (647012-20-2)

Guidance literature:

Multi-step reaction with 2 steps

1: Grubbs catalyst first generation / dichloromethane

2: Pd/C / 1,2-dichloro-ethane; ethanol

With Pd/C; Grubbs catalyst first generation; In ethanol; dichloromethane; 1,2-dichloro-ethane;

DOI:10.1021/om034121u

upstream raw materials:

(C₆H₅)2P(CH₂)2C(CH₃)2(CH₂)3CHCH₂

Downstream raw materials:

trans-(C₆F₅)(Ph₂P(CH₂)2C(CH₃)2(CH₂)3CH=CH₂)2Pt(CC)2H

trans-PtCl(C₆F₅)(PPh₂(CH₂)2C(CH₃)2(CH₂)8C(CH₃)2(CH₂)2PPh₂)