1,4-diiodo-2,5-bis{[3,4,5-tri(octadecoxy)phenyl]methoxy}benzene

Base Information

• Chemical Name: 1,4-diiodo-2,5-bis{[3,4,5-tri(octadecoxy)phenyl]methoxy}benzene
• CAS No.: 1443055-06-8
• Molecular Formula: C₁₂₈H₂₃₂I₂O₈
• Molecular Weight: 2153.05
• Mol file: 1443055-06-8.mol

Synonyms:1,4-diiodo-2,5-bis{[3,4,5-tri(octadecoxy)phenyl]methoxy}benzene

Chemical Property of 1,4-diiodo-2,5-bis{[3,4,5-tri(octadecoxy)phenyl]methoxy}benzene

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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Technology Process of 1,4-diiodo-2,5-bis{[3,4,5-tri(octadecoxy)phenyl]methoxy}benzene

There total 1 articles about 1,4-diiodo-2,5-bis{[3,4,5-tri(octadecoxy)phenyl]methoxy}benzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 82.0%

2,5-diiodo-1,4-hydroquinone (13064-64-7) + 5-(chloromethyl)-1,2,3-tris(octadecyloxy)benzene (256927-09-0) → 1,4-diiodo-2,5-bis{[3,4,5-tri(octadecoxy)phenyl]methoxy}benzene (1443055-06-8)

Guidance literature:

With potassium carbonate; In N,N-dimethyl-formamide; at 50 ℃; for 24h; Inert atmosphere;

DOI:10.1039/c3ob00041a

Reference yield: 88.0%

1,4-diiodo-2,5-bis{[3,4,5-tri(octadecoxy)phenyl]methoxy}benzene (1443055-06-8) + trimethylsilylacetylene (1066-54-2) → C138H250O8Si2

Guidance literature:

1,4-diiodo-2,5-bis{[3,4,5-tri(octadecoxy)phenyl]methoxy}benzene; With copper(l) iodide; diisopropylamine; In tetrahydrofuran; at 20 ℃; for 0.25h; Inert atmosphere;

trimethylsilylacetylene; In tetrahydrofuran; at 20 ℃; for 0.25h; Inert atmosphere;

With bis-triphenylphosphine-palladium(II) chloride; In tetrahydrofuran; at 20 ℃; for 3h; Inert atmosphere; Darkness;

DOI:10.1021/jacs.0c13326

Reference yield: 83.0%

1,4-diiodo-2,5-bis{[3,4,5-tri(octadecoxy)phenyl]methoxy}benzene (1443055-06-8) + 4-Ethynylbenzaldehyde (63697-96-1) → 1,4-bis(4′-benzaldehyde)-2,5-bis{[3,4,5-tri(octadecoxy)phenyl]methoxy}benzene

Guidance literature:

With bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; triethylamine; In tetrahydrofuran; at 40 ℃; for 9h;

DOI:10.1002/anie.201800980

upstream raw materials:

2,5-diiodo-1,4-hydroquinone

5-(chloromethyl)-1,2,3-tris(octadecyloxy)benzene

Downstream raw materials:

1,4-bis(4-pyridylethynyl)-2,5-bis{[3,4,5-tri(octadecoxy)phenyl]-methoxy}benzene