1-(carbobenzyloxy)-2-<4,8,12-trimethyl-3(E),7(E),11-tridecatrienyl>-4-piperidone

Base Information

Chemical Name:1-(carbobenzyloxy)-2-<4,8,12-trimethyl-3(E),7(E),11-tridecatrienyl>-4-piperidone
CAS No.:140176-45-0
Molecular Formula:C₂₉H₄₁NO₃
Molecular Weight:451.649
Hs Code.:

Synonyms:1-(carbobenzyloxy)-2-<4,8,12-trimethyl-3(E),7(E),11-tridecatrienyl>-4-piperidone

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 1-(carbobenzyloxy)-2-<4,8,12-trimethyl-3(E),7(E),11-tridecatrienyl>-4-piperidone

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Technology Process of 1-(carbobenzyloxy)-2-<4,8,12-trimethyl-3(E),7(E),11-tridecatrienyl>-4-piperidone

There total 9 articles about 1-(carbobenzyloxy)-2-<4,8,12-trimethyl-3(E),7(E),11-tridecatrienyl>-4-piperidone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 81.0%

: 135967-38-3
1-(carbobenzyloxy)-3-carbomethoxy-2-<4,8,12-trimethyl-3(E),7(E),11-tridecatrienyl>-4-piperidone

: 140176-45-0
1-(carbobenzyloxy)-2-<4,8,12-trimethyl-3(E),7(E),11-tridecatrienyl>-4-piperidone

Guidance literature:: With water; sodium chloride; In dimethyl sulfoxide; at 100 - 120 ℃; for 6h;
DOI:10.1021/jo00036a008

Reference yield:

: 140176-36-9
(10E)-13-bromo-2,6,10-trimethyltrideca-2,6,10-triene

: 140176-45-0
1-(carbobenzyloxy)-2-<4,8,12-trimethyl-3(E),7(E),11-tridecatrienyl>-4-piperidone

Guidance literature:: Multi-step reaction with 3 steps

1: 94 percent / NaI / acetone / 1.) r.t., 6 h, 2.) reflux, 2 h

3: 81 percent / NaCl, H₂O / dimethylsulfoxide / 6 h / 100 - 120 °C

With water; sodium iodide; sodium chloride; In dimethyl sulfoxide; acetone;
DOI:10.1021/jo00036a008

Reference yield:

: 62235-06-7
(3E,7E)-4,8,12-trimethyl-1,3,7,11-tridecatetraene

: 140176-45-0
1-(carbobenzyloxy)-2-<4,8,12-trimethyl-3(E),7(E),11-tridecatrienyl>-4-piperidone

Guidance literature:: Multi-step reaction with 5 steps

1: 1.) disiamylborane, 2.) H₂O₂, NaOH / 1.) THF

2: 88 percent / bromotriphenylphosphonium bromide, pyridine / CH₂Cl₂ / 5 h

3: 94 percent / NaI / acetone / 1.) r.t., 6 h, 2.) reflux, 2 h

5: 81 percent / NaCl, H₂O / dimethylsulfoxide / 6 h / 100 - 120 °C

With pyridine; sodium hydroxide; water; dihydrogen peroxide; bis-(1,2-dimethylpropyl)borane; bromotriphenylphosphonium bromide; sodium iodide; sodium chloride; In dichloromethane; dimethyl sulfoxide; acetone;
DOI:10.1021/jo00036a008