[S(S),N(E)]-2-methyl-N-[(4-chlorophenyl)methylene]-2-propanesulfinamide

Base Information

Chemical Name:[S(S),N(E)]-2-methyl-N-[(4-chlorophenyl)methylene]-2-propanesulfinamide
CAS No.:851513-47-8
Molecular Formula:C₁₁H₁₄ClNOS
Molecular Weight:243.757
Hs Code.:

Synonyms:[S(S),N(E)]-2-methyl-N-[(4-chlorophenyl)methylene]-2-propanesulfinamide

Suppliers and Price of [S(S),N(E)]-2-methyl-N-[(4-chlorophenyl)methylene]-2-propanesulfinamide

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
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price

Total 2 raw suppliers

Chemical Property of [S(S),N(E)]-2-methyl-N-[(4-chlorophenyl)methylene]-2-propanesulfinamide

Chemical Property:

Purity/Quality:: 99% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of [S(S),N(E)]-2-methyl-N-[(4-chlorophenyl)methylene]-2-propanesulfinamide

There total 1 articles about [S(S),N(E)]-2-methyl-N-[(4-chlorophenyl)methylene]-2-propanesulfinamide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

: 104-88-1
4-chlorobenzaldehyde

: 343338-28-3
(S)-2-methylpropane-2-sulfinamide

: 851513-47-8
[S(S),N(E)]-2-methyl-N-[(4-chlorophenyl)methylene]-2-propanesulfinamide

Guidance literature:: With caesium carbonate; In dichloromethane; for 7h; Inert atmosphere; Reflux;
DOI:10.1002/anie.201404007

Reference yield: 96.0%

: benzyl (tert-butoxycarbonyl)oxycarbamate

: 851513-47-8
[S(S),N(E)]-2-methyl-N-[(4-chlorophenyl)methylene]-2-propanesulfinamide

: (S_S,2R,3S)-N-tert-butanesulfinyl-O-[(tert-butyloxy)carbonyl]-3-(4-chlorophenyl)isoserine benzyl ester

Guidance literature:: With lithium hexamethyldisilazane; In tetrahydrofuran; at -78 ℃;
DOI:10.1021/jo052298n

Reference yield: 93.0%

: 13291-18-4
isopropenylmagnesium bromide

: 851513-47-8
[S(S),N(E)]-2-methyl-N-[(4-chlorophenyl)methylene]-2-propanesulfinamide

: (S)-N-((S)-1-(4-chlorophenyl)-2-methylallyl)-2-methylpropane-2-sulfinamide

Guidance literature:: isopropenylmagnesium bromide; With dimethyl zinc(II); In tetrahydrofuran; toluene; at 20 ℃; for 0.666667h; Inert atmosphere;

[S(S),N(E)]-2-methyl-N-[(4-chlorophenyl)methylene]-2-propanesulfinamide; In tetrahydrofuran; at -78 ℃; for 3h; diastereoselective reaction; Inert atmosphere;
DOI:10.1002/anie.201404007