Cotapp

Base Information

• Chemical Name: Cotapp
• CAS No.: 96481-61-7
• Molecular Formula: C₄₄H₃₂CoN₈
• Molecular Weight: 731.785
• Mol file: 96481-61-7.mol

Synonyms:cobalt tetrakis(2-aminophenyl)porphyrin;CoTAPP

Chemical Property of Cotapp

Chemical Property:

• Boiling Point: °Cat760mmHg
• Flash Point: °C
• PSA: 126.88000
• Density: g/cm³
• LogP: 7.09140
• Hydrogen Bond Donor Count: 4
• Hydrogen Bond Acceptor Count: 8
• Rotatable Bond Count: 4
• Exact Mass: 731.208187
• Heavy Atom Count: 53
• Complexity: 953

Purity/Quality:

98.5% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=C(C(=C1)C2=C3C=CC(=C(C4=CC=C([N-]4)C(=C5C=CC(=N5)C(=C6C=CC2=N6)C7=CC=CC=C7N)C8=CC=CC=C8N)C9=CC=CC=C9N)[N-]3)N.[Co+2]

Technology Process of Cotapp

There total 1 articles about Cotapp which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

cobalt(II) acetate dihydrate + cis-α,α,α,α-atropisomer 5,10,15,20-tetrakis(2-aminophenyl)porphyrin (52199-35-6,68070-27-9,68070-28-0,68070-29-1,68070-30-4) → poly(cobalt tetra(o-aminophenyl)porphyrin) (96481-61-7,141553-20-0)

Guidance literature:

In N,N-dimethyl-formamide; free porphyrin metallated with Co acetate in DMF; chromy.(silica gel - chloroform);

DOI:10.1016/j.molcata.2006.06.011

Reference yield:

poly(cobalt tetra(o-aminophenyl)porphyrin) (96481-61-7,141553-20-0) + acetic acid (64-19-7,77671-22-8) → 5,10,15,20-tetra-o-aminophenylporphyrinatocobalt(III) acetate (1001617-49-7)

Guidance literature:

In toluene; suspn. of Co complex in toluene treated with 20 equiv. of glacial aceticacid, stirred at room temp. for 4 h; evapd.(vac.);

DOI:10.1016/j.molcata.2006.06.011

upstream raw materials:

cis-α,α,α,α-atropisomer 5,10,15,20-tetrakis(2-aminophenyl)porphyrin

Downstream raw materials:

5,10,15,20-tetra-o-aminophenylporphyrinatocobalt(III) acetate

Refernces