Technology Process of C32H52O10SSi2
There total 13 articles about C32H52O10SSi2 which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
With
triethylamine;
In
dichloromethane;
at 0 - 20 ℃;
for 1.5h;
Inert atmosphere;
DOI:10.1021/ol301090v
- Guidance literature:
-
Multi-step reaction with 7 steps
1: 2,6-dimethylpyridine / dichloromethane / 0 - 20 °C / Inert atmosphere
2: potassium osmate monohydrate; 4-methylmorpholine N-oxide / water; acetone / 4 h / 20 °C
3: 2,6-dimethylpyridine / dichloromethane / 0.42 h / -30 °C / Inert atmosphere
4: dmap; magnesium bromide diethyl etherate; N-ethyl-N,N-diisopropylamine / dichloromethane / 144 h / 20 °C / Inert atmosphere
5: potassium osmate monohydrate; 4-methylmorpholine N-oxide / water; acetone / 1 h / 20 °C
6: pyridinium p-toluenesulfonate / methanol / 3.5 h / 0 °C / Inert atmosphere
7: triethylamine / dichloromethane / 1.5 h / 0 - 20 °C / Inert atmosphere
With
2,6-dimethylpyridine; dmap; magnesium bromide diethyl etherate; potassium osmate monohydrate; pyridinium p-toluenesulfonate; 4-methylmorpholine N-oxide; triethylamine; N-ethyl-N,N-diisopropylamine;
In
methanol; dichloromethane; water; acetone;
6: Barton-McCombie deoxygenation;
DOI:10.1021/ol301090v
- Guidance literature:
-
Multi-step reaction with 2 steps
1: pyridinium p-toluenesulfonate / methanol / 3.5 h / 0 °C / Inert atmosphere
2: triethylamine / dichloromethane / 1.5 h / 0 - 20 °C / Inert atmosphere
With
pyridinium p-toluenesulfonate; triethylamine;
In
methanol; dichloromethane;
1: Barton-McCombie deoxygenation;
DOI:10.1021/ol301090v
