(2S,4aR,6R,7R,8R,8aR)-2-Phenyl-6-[(1R,2R)-2-((2S,3S,4R,5R,6S)-3,4,5-tris-benzyloxy-6-methyl-tetrahydro-pyran-2-yloxy)-cyclohexyloxy]-hexahydro-pyrano[3,2-d][1,3]dioxine-7,8-diol

Base Information

Chemical Name:(2S,4aR,6R,7R,8R,8aR)-2-Phenyl-6-[(1R,2R)-2-((2S,3S,4R,5R,6S)-3,4,5-tris-benzyloxy-6-methyl-tetrahydro-pyran-2-yloxy)-cyclohexyloxy]-hexahydro-pyrano[3,2-d][1,3]dioxine-7,8-diol
CAS No.:187402-06-8
Molecular Formula:C₄₆H₅₄O₁₁
Molecular Weight:782.928
Hs Code.:

(2S,4aR,6R,7R,8R,8aR)-2-Phenyl-6-[(1R,2R)-2-((2S,3S,4R,5R,6S)-3,4,5-tris-benzyloxy-6-methyl-tetrahydro-pyran-2-yloxy)-cyclohexyloxy]-hexahydro-pyrano[3,2-d][1,3]dioxine-7,8-diol

Synonyms:(2S,4aR,6R,7R,8R,8aR)-2-Phenyl-6-[(1R,2R)-2-((2S,3S,4R,5R,6S)-3,4,5-tris-benzyloxy-6-methyl-tetrahydro-pyran-2-yloxy)-cyclohexyloxy]-hexahydro-pyrano[3,2-d][1,3]dioxine-7,8-diol

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Chemical Property of (2S,4aR,6R,7R,8R,8aR)-2-Phenyl-6-[(1R,2R)-2-((2S,3S,4R,5R,6S)-3,4,5-tris-benzyloxy-6-methyl-tetrahydro-pyran-2-yloxy)-cyclohexyloxy]-hexahydro-pyrano[3,2-d][1,3]dioxine-7,8-diol

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Technology Process of (2S,4aR,6R,7R,8R,8aR)-2-Phenyl-6-[(1R,2R)-2-((2S,3S,4R,5R,6S)-3,4,5-tris-benzyloxy-6-methyl-tetrahydro-pyran-2-yloxy)-cyclohexyloxy]-hexahydro-pyrano[3,2-d][1,3]dioxine-7,8-diol

There total 1 articles about (2S,4aR,6R,7R,8R,8aR)-2-Phenyl-6-[(1R,2R)-2-((2S,3S,4R,5R,6S)-3,4,5-tris-benzyloxy-6-methyl-tetrahydro-pyran-2-yloxy)-cyclohexyloxy]-hexahydro-pyrano[3,2-d][1,3]dioxine-7,8-diol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

: 1125-88-8
benzaldehyde dimethyl acetal

: 172147-75-0
(2R,3R,4S,5R,6R)-2-Hydroxymethyl-6-[(1R,2R)-2-((2S,3S,4R,5R,6S)-3,4,5-tris-benzyloxy-6-methyl-tetrahydro-pyran-2-yloxy)-cyclohexyloxy]-tetrahydro-pyran-3,4,5-triol

: 187402-06-8
(2S,4aR,6R,7R,8R,8aR)-2-Phenyl-6-[(1R,2R)-2-((2S,3S,4R,5R,6S)-3,4,5-tris-benzyloxy-6-methyl-tetrahydro-pyran-2-yloxy)-cyclohexyloxy]-hexahydro-pyrano[3,2-d][1,3]dioxine-7,8-diol

Guidance literature:: With camphor-10-sulfonic acid; In acetonitrile; at 35 ℃; for 0.75h;
DOI:10.1002/chem.19970031006

Reference yield:

: 187402-06-8
(2S,4aR,6R,7R,8R,8aR)-2-Phenyl-6-[(1R,2R)-2-((2S,3S,4R,5R,6S)-3,4,5-tris-benzyloxy-6-methyl-tetrahydro-pyran-2-yloxy)-cyclohexyloxy]-hexahydro-pyrano[3,2-d][1,3]dioxine-7,8-diol

: sodium (2S) 2-O-{1-O-[(1R,2R) 2-O-(α-L-fucopyranosyl)cyclohexyl]-β-D-galactopyranos-3-yl}-3-phenylpropanoate

Guidance literature:: Multi-step reaction with 2 steps

1: 1.) Bu₂SnO, 2.) CsF / 1.) MeOH, reflux, 2 h, 2.) DME, r.t., 2 h

2: 78 percent / H₂, aq. AcOH / 20percent Pd(OH)2/C / dioxane / 7 h / 750.06 Torr

With hydrogen; di(n-butyl)tin oxide; acetic acid; cesium fluoride; palladium dihydroxide; In 1,4-dioxane;
DOI:10.1002/chem.19970031006

Reference yield:

: 111437-25-3
benzyl (R)-(+)-3-phenyl-2-(trifluoromethylsulfonyloxy)propanoate

: 187402-06-8
(2S,4aR,6R,7R,8R,8aR)-2-Phenyl-6-[(1R,2R)-2-((2S,3S,4R,5R,6S)-3,4,5-tris-benzyloxy-6-methyl-tetrahydro-pyran-2-yloxy)-cyclohexyloxy]-hexahydro-pyrano[3,2-d][1,3]dioxine-7,8-diol

: 187402-09-1
(S)-2-{(2S,4aR,6R,7R,8R,8aS)-7-Hydroxy-2-phenyl-6-[(1R,2R)-2-((2S,3S,4R,5R,6S)-3,4,5-tris-benzyloxy-6-methyl-tetrahydro-pyran-2-yloxy)-cyclohexyloxy]-hexahydro-pyrano[3,2-d][1,3]dioxin-8-yloxy}-3-phenyl-propionic acid benzyl ester

Guidance literature:: With di(n-butyl)tin oxide; cesium fluoride; Yield given. Multistep reaction; 1.) MeOH, reflux, 2 h, 2.) DME, r.t., 2 h;
DOI:10.1002/chem.19970031006