Tricyclo(8.2.2.24,7)hexadeca-4,6,10,12,13,15-hexaene, 5,11-dimethyl-

Base Information

• Chemical Name: Tricyclo(8.2.2.24,7)hexadeca-4,6,10,12,13,15-hexaene, 5,11-dimethyl-
• CAS No.: 80548-37-4
• Molecular Formula: C18H20
• Molecular Weight: 236.3514
• DSSTox Substance ID: DTXSID80946750
• Nikkaji Number: J1.037.887G
• Wikidata: Q82924430
• Mol file: 80548-37-4.mol

Synonyms:23927-47-1;Tricyclo(8.2.2.24,7)hexadeca-4,6,10,12,13,15-hexaene, 5,11-dimethyl-;Tricyclo(8.2.2.24,7)hexadeca-4,6,10,12,13,15-hexaene, 5,12-dimethyl-;Tricyclo(8.2.2.24,7)hexadeca-4,6,10,12,13,15-hexaene, 5,15-dimethyl-;Tricyclo[8.2.2.24,7]hexadeca-4,6,10,12,13,15-hexaene, 5,15-dimethyl-;Tricyclo[8.2.2.24,7]hexadeca-4,6,10,12,13,15-hexaene, 5,11-dimethyl-;Tricyclo[8.2.2.24,7]hexadeca-4,6,10,12,13,15-hexaene, 5,12-dimethyl-;2,5-Dimethyl[2.2]paracyclophane;DTXSID80946750;2,6-Dimethyl[2.2]paracyclophane;2,5'-Dimethyl[2.2]paracyclophane;35117-18-1;80548-37-4;5,11-Dimethyltricyclo[8.2.2.2~4,7~]hexadeca-1(12),4,6,10,13,15-hexaene

Chemical Property of Tricyclo(8.2.2.24,7)hexadeca-4,6,10,12,13,15-hexaene, 5,11-dimethyl-

Chemical Property:

• Vapor Pressure: 6.53E-05mmHg at 25°C
• Boiling Point: 355.2°C at 760 mmHg
• Flash Point: 180.7°C
• Density: 1.009g/cm³
• XLogP3: 5.2
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 0
• Exact Mass: 236.156500638
• Heavy Atom Count: 18
• Complexity: 241

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Canonical SMILES: CC1=C2CCC3=CC(=C(CCC(=C1)C=C2)C=C3)C

Technology Process of Tricyclo(8.2.2.24,7)hexadeca-4,6,10,12,13,15-hexaene, 5,11-dimethyl-

There total 5 articles about Tricyclo(8.2.2.24,7)hexadeca-4,6,10,12,13,15-hexaene, 5,11-dimethyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

methylfurmethide (1197-60-0) + (3,4-Dimethyl-benzyl)-trimethyl-ammonium; iodide (129786-02-3) → [2.2](2.5)furanocyclophane (5088-46-0,73650-68-7) + 4,12-dimethyl<2.2>paracyclophane (344938-52-9,23927-47-1) + 5,12-Dimethyltricyclo[8.2.2.24,7]hexadeca-4,6,10,12,13,15-hexaene (80548-37-4) + 3,6-diketo-10-methyl<8>paracyclophane (129786-08-9)

Guidance literature:

With silver(l) oxide; Multistep reaction; 2) toluene, heating;

DOI:10.1021/ja00177a013

Reference yield:

methylfurmethide (1197-60-0) + (3,4-Dimethyl-benzyl)-trimethyl-ammonium; iodide (129786-02-3) → [2.2](2.5)furanocyclophane (5088-46-0,73650-68-7) + 4,12-dimethyl<2.2>paracyclophane (344938-52-9,23927-47-1) + 5,12-Dimethyltricyclo[8.2.2.24,7]hexadeca-4,6,10,12,13,15-hexaene (80548-37-4) + 4-methyl<2>paracyclo<2>(2,5)furanophane (129786-07-8)

Guidance literature:

With silver(l) oxide; Multistep reaction; 2) toluene, heating;

DOI:10.1021/ja00177a013

Reference yield:

pseudogem-Bis(bromomethyl)<2.2>paracyclophane (43045-00-7) → 5,12-Dimethyltricyclo[8.2.2.24,7]hexadeca-4,6,10,12,13,15-hexaene (80548-37-4)

Guidance literature:

With lithium aluminium tetrahydride; In tetrahydrofuran;

DOI:10.1002/hlca.19810640704

upstream raw materials:

pseudogem-Bis(bromomethyl)<2.2>paracyclophane

methylfurmethide

(3,4-Dimethyl-benzyl)-trimethyl-ammonium; iodide

<2.2>Paracyclophan-4,13-dicarbonsaeure-dimethylester