[Ru(2,2':6',2''-terpyridine)(2,2,6,6-tetramethyl-3,5-heptadione)(TMSepcyd)]

Base Information

Chemical Name:[Ru(2,2':6',2''-terpyridine)(2,2,6,6-tetramethyl-3,5-heptadione)(TMSepcyd)]
CAS No.:928780-58-9
Molecular Formula:C₃₈H₄₃N₅O₂RuSi
Molecular Weight:730.947
Hs Code.:

Synonyms:[Ru(2,2':6',2''-terpyridine)(2,2,6,6-tetramethyl-3,5-heptadione)(TMSepcyd)]

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Chemical Property of [Ru(2,2':6',2''-terpyridine)(2,2,6,6-tetramethyl-3,5-heptadione)(TMSepcyd)]

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Technology Process of [Ru(2,2':6',2''-terpyridine)(2,2,6,6-tetramethyl-3,5-heptadione)(TMSepcyd)]

There total 1 articles about [Ru(2,2':6',2''-terpyridine)(2,2,6,6-tetramethyl-3,5-heptadione)(TMSepcyd)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

: 916649-54-2
[Ru(2,2':6,2''-terpyridine)(2,2,6,6-tetramethyl-3,5-heptadionate)(4-iodophenylcyanamide^(1-))]

: 1066-54-2
trimethylsilylacetylene

: 928780-58-9
[Ru(2,2':6',2''-terpyridine)(2,2,6,6-tetramethyl-3,5-heptadione)(TMSepcyd)]

Guidance literature:: With catalyst:[Pd(PPh₃)2Cl₂]/CuI; In N,N-dimethyl-formamide; in a Schlenk tube, Ru-complex, CuI and Pd-complex were placed in soln. DMF/piperidine (4:1) degassed with Ar, (CH3)3SiC2H was added under Ar, the mixt. was stirred at room temp. for 3.5 h; evapd. to dryness, column chromy. (weakly acidic alumina, CH2Cl2/ethanol99.5:0.5); elem. anal.;
DOI:10.1021/ja067255i

Reference yield:

: 928780-58-9
[Ru(2,2':6',2''-terpyridine)(2,2,6,6-tetramethyl-3,5-heptadione)(TMSepcyd)]

: [Ru(2,2':6',2''-terpyridine)(2,2,6,6-tetramethyl-3,5-heptadione)(epcyd)]

Guidance literature:: With potassium carbonate; In methanol; K2CO3 was added to a soln. of complex in methanol degassed with Ar, the mixt. was stirred under Ar at 40°C for 2.5 h; evapd. to dryness;
DOI:10.1021/ja067255i