(+)-benzyl (2S,3S,6R,8S)-8-O-((2'R,3'R,6'S,8'R)-8'-O'-{(2S,3S,6R,8S)-8-O-[(2R,3R,6S,8R)-8-O-tert-butyldimethylsilylbishomononactoyl]bishomononactoyl}bisho-mononactoyl)bishomononactate

Base Information

Chemical Name:(+)-benzyl (2S,3S,6R,8S)-8-O-((2'R,3'R,6'S,8'R)-8'-O'-{(2S,3S,6R,8S)-8-O-[(2R,3R,6S,8R)-8-O-tert-butyldimethylsilylbishomononactoyl]bishomononactoyl}bisho-mononactoyl)bishomononactate
CAS No.:391198-99-5
Molecular Formula:C₆₁H₁₀₂O₁₃Si
Molecular Weight:1071.56
Hs Code.:

(+)-benzyl (2S,3S,6R,8S)-8-O-((2'R,3'R,6'S,8'R)-8'-O'-{(2S,3S,6R,8S)-8-O-[(2R,3R,6S,8R)-8-O-tert-butyldimethylsilylbishomononactoyl]bishomononactoyl}bisho-mononactoyl)bishomononactate

Synonyms:(+)-benzyl (2S,3S,6R,8S)-8-O-((2'R,3'R,6'S,8'R)-8'-O'-{(2S,3S,6R,8S)-8-O-[(2R,3R,6S,8R)-8-O-tert-butyldimethylsilylbishomononactoyl]bishomononactoyl}bisho-mononactoyl)bishomononactate

Suppliers and Price of (+)-benzyl (2S,3S,6R,8S)-8-O-((2'R,3'R,6'S,8'R)-8'-O'-{(2S,3S,6R,8S)-8-O-[(2R,3R,6S,8R)-8-O-tert-butyldimethylsilylbishomononactoyl]bishomononactoyl}bisho-mononactoyl)bishomononactate

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Chemical Property of (+)-benzyl (2S,3S,6R,8S)-8-O-((2'R,3'R,6'S,8'R)-8'-O'-{(2S,3S,6R,8S)-8-O-[(2R,3R,6S,8R)-8-O-tert-butyldimethylsilylbishomononactoyl]bishomononactoyl}bisho-mononactoyl)bishomononactate

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Technology Process of (+)-benzyl (2S,3S,6R,8S)-8-O-((2'R,3'R,6'S,8'R)-8'-O'-{(2S,3S,6R,8S)-8-O-[(2R,3R,6S,8R)-8-O-tert-butyldimethylsilylbishomononactoyl]bishomononactoyl}bisho-mononactoyl)bishomononactate

There total 17 articles about (+)-benzyl (2S,3S,6R,8S)-8-O-((2'R,3'R,6'S,8'R)-8'-O'-{(2S,3S,6R,8S)-8-O-[(2R,3R,6S,8R)-8-O-tert-butyldimethylsilylbishomononactoyl]bishomononactoyl}bisho-mononactoyl)bishomononactate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

: 391198-96-2
(-)-benzyl (2S,3S,6R,8S)-8-O-[(2'R,3'R,6'S,8'R)-bishomononactoyl]bishomononactate

: 391198-98-4
(+)-S-2-pyridyl (2S,3S,6R,8S)-[(2'R,3'R,6'S,8'R)-8'-O'-tert-buthydimethylsilylbishomononactoyl]thiobishomononactate

: 391198-99-5
(+)-benzyl (2S,3S,6R,8S)-8-O-((2'R,3'R,6'S,8'R)-8'-O'-{(2S,3S,6R,8S)-8-O-[(2R,3R,6S,8R)-8-O-tert-butyldimethylsilylbishomononactoyl]bishomononactoyl}bisho-mononactoyl)bishomononactate

Guidance literature:: With silver perchlorate;
DOI:10.1271/bbb.65.2118

Reference yield:

: 391198-93-9,17488-13-0
(-)-bishomononactic acid

: 391198-99-5
(+)-benzyl (2S,3S,6R,8S)-8-O-((2'R,3'R,6'S,8'R)-8'-O'-{(2S,3S,6R,8S)-8-O-[(2R,3R,6S,8R)-8-O-tert-butyldimethylsilylbishomononactoyl]bishomononactoyl}bisho-mononactoyl)bishomononactate

Guidance literature:: Multi-step reaction with 6 steps

1.1: t-BuOK / dimethylformamide / 65 °C

2.1: imidazole / tetrahydrofuran

3.1: H₂ / 10 percent Pd/C / methanol

4.1: (PyS)2; PPh₃ / toluene / Heating

4.2: 86 percent / AgClO₄ / toluene

5.1: 100 percent / HF / acetonitrile

6.1: 90 percent / AgClO₄

With 1H-imidazole; hydrogen fluoride; potassium tert-butylate; hydrogen; silver perchlorate; triphenylphosphine; palladium on activated charcoal; In tetrahydrofuran; methanol; N,N-dimethyl-formamide; toluene; acetonitrile;
DOI:10.1271/bbb.65.2118

Reference yield:

: 391198-91-7,17488-13-0
(+)-bishomononactic acid

: 391198-99-5
(+)-benzyl (2S,3S,6R,8S)-8-O-((2'R,3'R,6'S,8'R)-8'-O'-{(2S,3S,6R,8S)-8-O-[(2R,3R,6S,8R)-8-O-tert-butyldimethylsilylbishomononactoyl]bishomononactoyl}bisho-mononactoyl)bishomononactate

Guidance literature:: Multi-step reaction with 5 steps

1.1: 86 percent / t-BuOK / dimethylformamide / 65 °C

2.1: (PyS)2; PPh₃ / toluene / Heating

2.2: 86 percent / AgClO₄ / toluene

3.1: 100 percent / H₂ / Pd-C / methanol

4.1: PPh₃

5.1: 90 percent / AgClO₄

With potassium tert-butylate; hydrogen; silver perchlorate; triphenylphosphine; palladium on activated charcoal; In methanol; N,N-dimethyl-formamide; toluene;
DOI:10.1271/bbb.65.2118