(2-Chlorobenzyl)triphenylphosphonium Chloride

Base Information

Chemical Name:(2-Chlorobenzyl)triphenylphosphonium Chloride
CAS No.:18583-55-6
Molecular Formula:C25H21 Cl P . Cl
Molecular Weight:423.322
Hs Code.:2931900090
European Community (EC) Number:679-954-0
NSC Number:210534
UNII:BF8XZH2GMF
DSSTox Substance ID:DTXSID70940005
ChEMBL ID:CHEMBL3229241
Mol file:18583-55-6.mol

Synonyms:(2-Chlorobenzyl)triphenylphosphonium Chloride;18583-55-6;(2-chlorophenyl)methyl-triphenylphosphanium;chloride;NSC-210534;2-chlorobenzyltriphenylphosphonium chloride;NSC210534;P(Cc1ccccc1Cl)(c2ccccc2)(c3ccccc3)c4ccccc4;BF8XZH2GMF;Triphenyl(2-chlorobenzyl)phosphonium Chloride;(2-chlorophenyl)methyl-triphenylphosphanium chloride;[(2-chlorophenyl)methyl]triphenylphosphanium chloride;SCHEMBL2720227;CHEMBL3229241;DTXSID70940005;VRAAQIWOSHYDHE-UHFFFAOYSA-M;MFCD00054629;AKOS015833223;2-chlorobenzyl-triphenylphosphonium chloride;C1759;CS-0179381;(2-chlorobenzyl)(triphenyl)phosphonium chloride;S12018;Phosphonium, (o-chlorobenzyl)triphenyl-, chloride;J-011913;[(2-Chlorophenyl)methyl](triphenyl)phosphanium chloride;(2-CHLOROBENZYL)TRIPHENYLPHOSPHONIUMCHLORIDEHYDRATE;Phosphonium, [(2-chlorophenyl)methyl]triphenyl-, chloride (1:1)

Suppliers and Price of (2-Chlorobenzyl)triphenylphosphonium Chloride

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

TRC
(2-Chlorobenzyl)triphenylphosphonium Chloride
10g
$ 970.00

TCI Chemical
(2-Chlorobenzyl)triphenylphosphonium Chloride >98.0%(HPLC)
25g
$ 171.00

Chem-Impex
(2-Chlorobenzyl)triphenylphosphoniumchloride,98%(HPLC) 98%(HPLC)
25G
$ 106.40

Chem-Impex
(2-Chlorobenzyl)triphenylphosphoniumchloride,98%(HPLC) 98%(HPLC)
5G
$ 50.40

Chem-Impex
(2-Chlorobenzyl)triphenylphosphoniumchloride,≥98%(HPLC) ≥98%(HPLC)
1G
$ 17.47

Chem-Impex
(2-Chlorobenzyl)triphenylphosphoniumchloride,98%(HPLC) 98%(HPLC)
100G
$ 313.60

American Custom Chemicals Corporation
(2-CHLOROBENZYL)TRIPHENYLPHOSPHONIUM CHLORIDE HYDRATE 95.00%
25G
$ 1188.19

Alichem
(2-Chlorobenzyl)triphenylphosphoniumchloridehydrate
500g
$ 926.10

AK Scientific
(2-Chlorobenzyl)triphenylphosphoniumchloridehydrate
25g
$ 243.00

AK Scientific
(2-Chlorobenzyl)triphenylphosphonium Chloride
25g
$ 243.00

Total 16 raw suppliers

Chemical Property of (2-Chlorobenzyl)triphenylphosphonium Chloride

Chemical Property:

Melting Point:243-245 °C
Boiling Point:°Cat760mmHg
Flash Point:°C
PSA：13.59000
Density:g/cm³
LogP:2.83810
Storage Temp.:Inert atmosphere,Room Temperature
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:1
Rotatable Bond Count:5
Exact Mass:422.0757931
Heavy Atom Count:28
Complexity:386

Purity/Quality:

99%, ^*data from raw suppliers

(2-Chlorobenzyl)triphenylphosphonium Chloride ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:Xn
Statements: 36/37/38-20/22
Safety Statements: 36/37/39-26

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C1=CC=C(C=C1)[P+](CC2=CC=CC=C2Cl)(C3=CC=CC=C3)C4=CC=CC=C4.[Cl-]
Uses (2-Chlorobenzyl)triphenylphosphonium Chloride is a reagent in Wittig reaction with imidazolecarboxaldehyde to synthesize elevel 4-(5)arylethenylimidazoles.

Technology Process of (2-Chlorobenzyl)triphenylphosphonium Chloride

There total 2 articles about (2-Chlorobenzyl)triphenylphosphonium Chloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 78.5%

: 611-19-8
1-chloro-2-(chloromethyl)benzene

: 603-35-0
triphenylphosphine

: 18583-55-6
2-chlorobenzyl-triphenylphosphonium chloride

Guidance literature:: In xylene; Heating / reflux;

Reference yield:

: 18583-55-6
2-chlorobenzyl-triphenylphosphonium chloride

Guidance literature:: o-Cl-C6H4-CH2Cl, PPh3 /DMF, Δ;

Reference yield: 98.0%

: 869106-75-2
1-(3-methoxypropyl)-1H-pyrrole-2-carbaldehyde

: 18583-55-6
2-chlorobenzyl-triphenylphosphonium chloride

: 869106-77-4
2-[2-(2-chlorophenyl)vinyl]-1-(3-methoxypropyl)-1H-pyrrole

Guidance literature:: 2-chlorobenzyl-triphenylphosphonium chloride; With lithium diisopropyl amide; In tetrahydrofuran; n-heptane; at 20 ℃; for 1h;

1-(3-methoxypropyl)-1H-pyrrole-2-carbaldehyde; In tetrahydrofuran; n-heptane; for 19h; Product distribution / selectivity;