methyl (methyl 2,3-di-O-acetyl-β-D-glucopyranosyluronate)-(1->4)-2,6-di-O-benzyl-3-deoxy-3-C-(methyl sulfonatomethyl)-α-D-glucopyranoside

Base Information

Chemical Name:methyl (methyl 2,3-di-O-acetyl-β-D-glucopyranosyluronate)-(1->4)-2,6-di-O-benzyl-3-deoxy-3-C-(methyl sulfonatomethyl)-α-D-glucopyranoside
CAS No.:1261355-87-6
Molecular Formula:C₃₄H₄₄O₁₆S
Molecular Weight:740.78
Hs Code.:

Synonyms:methyl (methyl 2,3-di-O-acetyl-β-D-glucopyranosyluronate)-(1->4)-2,6-di-O-benzyl-3-deoxy-3-C-(methyl sulfonatomethyl)-α-D-glucopyranoside

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of methyl (methyl 2,3-di-O-acetyl-β-D-glucopyranosyluronate)-(1->4)-2,6-di-O-benzyl-3-deoxy-3-C-(methyl sulfonatomethyl)-α-D-glucopyranoside

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Technology Process of methyl (methyl 2,3-di-O-acetyl-β-D-glucopyranosyluronate)-(1->4)-2,6-di-O-benzyl-3-deoxy-3-C-(methyl sulfonatomethyl)-α-D-glucopyranoside

There total 7 articles about methyl (methyl 2,3-di-O-acetyl-β-D-glucopyranosyluronate)-(1->4)-2,6-di-O-benzyl-3-deoxy-3-C-(methyl sulfonatomethyl)-α-D-glucopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 79.0%

: C₃₃H₄₂O₁₆S

: 856191-85-0
diazomethane diethyl ether

: 1261355-87-6
methyl (methyl 2,3-di-O-acetyl-β-D-glucopyranosyluronate)-(1->4)-2,6-di-O-benzyl-3-deoxy-3-C-(methyl sulfonatomethyl)-α-D-glucopyranoside

Guidance literature:: In tetrahydrofuran;
DOI:10.1016/j.tetlet.2010.10.042

Reference yield:

: 186581-53-3,908094-01-9,334-88-3
diazomethane

: C₃₃H₄₂O₁₆S

: 1261355-87-6
methyl (methyl 2,3-di-O-acetyl-β-D-glucopyranosyluronate)-(1->4)-2,6-di-O-benzyl-3-deoxy-3-C-(methyl sulfonatomethyl)-α-D-glucopyranoside

Guidance literature:: In tetrahydrofuran; diethyl ether; at 0 ℃;
DOI:10.1016/j.tet.2012.06.081

Reference yield:

: 1261355-83-2
methyl (2,3-di-O-acetyl-4,6-O-(4-methoxybenzylidene)-β-D-glucopyranosyl)-(1->4)-2,6-di-O-benzyl-3-deoxy-3-C-(methyl sulfonatomethyl)-α-D-glucopyranoside

: 1261355-87-6
methyl (methyl 2,3-di-O-acetyl-β-D-glucopyranosyluronate)-(1->4)-2,6-di-O-benzyl-3-deoxy-3-C-(methyl sulfonatomethyl)-α-D-glucopyranoside

Guidance literature:: Multi-step reaction with 3 steps

1: acetic acid / 1 h / 20 °C

2: 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical; [bis(acetoxy)iodo]benzene / dichloromethane; water / 1 h

3: tetrahydrofuran; diethyl ether / 0 °C

With 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical; [bis(acetoxy)iodo]benzene; acetic acid; In tetrahydrofuran; diethyl ether; dichloromethane; water;
DOI:10.1016/j.tet.2012.06.081