trans-[ruthenium(II)Cl(1,2-phenylenebis(dimethylarsine))(2,2'-bipyridine)triphenylphosphine]PF₆

Base Information

• Chemical Name: trans-[ruthenium(II)Cl(1,2-phenylenebis(dimethylarsine))(2,2'-bipyridine)triphenylphosphine]PF₆
• CAS No.: 299397-60-7
• Molecular Formula: C₃₈H₃₉As₂ClN₂PRu*F₆P
• Molecular Weight: 986.045
• Mol file: 299397-60-7.mol

Synonyms:trans-[ruthenium(II)Cl(1,2-phenylenebis(dimethylarsine))(2,2'-bipyridine)triphenylphosphine]PF₆

Chemical Property of trans-[ruthenium(II)Cl(1,2-phenylenebis(dimethylarsine))(2,2'-bipyridine)triphenylphosphine]PF₆

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of trans-[ruthenium(II)Cl(1,2-phenylenebis(dimethylarsine))(2,2'-bipyridine)triphenylphosphine]PF₆

There total 1 articles about trans-[ruthenium(II)Cl(1,2-phenylenebis(dimethylarsine))(2,2'-bipyridine)triphenylphosphine]PF₆ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

trans-[ruthenium(II)Cl(1,2-phenylenebis(dimethylarsine))(2,2'-bipyridine)(nitrosyl)][PF6]2 + triphenylphosphine (603-35-0) → trans-[ruthenium(II)Cl(1,2-phenylenebis(dimethylarsine))(2,2'-bipyridine)triphenylphosphine]PF6 (299397-60-7)

Guidance literature:

With NaN₃; In butanone; under Ar; acetone soln. of Ru complex and NaN3 stirred (room temp., 2 h); 2-butanone sol. of PPh3 added; acetone removed (vac.); soln. refluxed(2 h); evapd. to small vol. (vac.); Et2O added; ppt. filtered off, washed (Et2O), dried; repptd. (CH3CN/Et2O); elem.anal.;

DOI:10.1016/S0277-5387(00)00369-7

Reference yield: 64.0%

trans-[ruthenium(II)Cl(1,2-phenylenebis(dimethylarsine))(2,2'-bipyridine)triphenylphosphine]PF6 (299397-60-7) + acetonitrile (75-05-8,26809-02-9) → trans-[ruthenium(II)(1,2-phenylenebis(dimethylarsine))(2,2'-bipyridine)(triphenylphosphine)acetonitrile][PF6]2

Guidance literature:

With AgCF₃CO₂; NH₄PF₆; In water; acetone; byproducts: AgCl; under Ar; acetone soln. of Ru complex, AgCF3CO2, acetonitrile refluxed (75 min); H2O added; refluxed (3 h); filtered; aq. NH4PF6 and H2O added; ppt. filtered off, washed (water), dried; repptd. (acetone/Et2O); elem.anal.;

DOI:10.1016/S0277-5387(00)00369-7

upstream raw materials:

triphenylphosphine