(R,R)-(+)-2-(d-10-camphorsulfonyl)-3-(2-chloro-5-nitrophenyl)oxaziridine

Base Information

Chemical Name:(R,R)-(+)-2-(d-10-camphorsulfonyl)-3-(2-chloro-5-nitrophenyl)oxaziridine
CAS No.:81369-89-3
Molecular Formula:C₁₇H₁₉ClN₂O₆S
Molecular Weight:414.867
Hs Code.:

Synonyms:(R,R)-(+)-2-(d-10-camphorsulfonyl)-3-(2-chloro-5-nitrophenyl)oxaziridine

Suppliers and Price of (R,R)-(+)-2-(d-10-camphorsulfonyl)-3-(2-chloro-5-nitrophenyl)oxaziridine

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

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Chemicals and raw materials
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Total 1 raw suppliers

Chemical Property of (R,R)-(+)-2-(d-10-camphorsulfonyl)-3-(2-chloro-5-nitrophenyl)oxaziridine

Chemical Property:

Purity/Quality:: 98% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of (R,R)-(+)-2-(d-10-camphorsulfonyl)-3-(2-chloro-5-nitrophenyl)oxaziridine

There total 5 articles about (R,R)-(+)-2-(d-10-camphorsulfonyl)-3-(2-chloro-5-nitrophenyl)oxaziridine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 40.0%

: 82679-82-1
N-(2-chloro-5-nitrobenzylidene)-d-10-camphorsulfonamide

: 81310-08-9
(-)-(S,S)-3-(2-Chloro-5-nitrophenyl)-2-(d-2-oxo-10-bornylsulfonyl)oxaziridine

: 81369-89-3
(R,R)-(+)-2-(d-10-camphorsulfonyl)-3-(2-chloro-5-nitrophenyl)oxaziridine

Guidance literature:: With sodium hydrogencarbonate; 3-chloro-benzenecarboperoxoic acid; In chloroform; for 3.5h; Ambient temperature;
DOI:10.1021/ja00384a028

Reference yield:

: 3144-16-9,61380-66-3
(1S)-10-camphorsulfonic acid

: 81369-89-3
(R,R)-(+)-2-(d-10-camphorsulfonyl)-3-(2-chloro-5-nitrophenyl)oxaziridine

Guidance literature:: Multi-step reaction with 4 steps

1: thionyl chloride / 1.) room temperature, 10 min, 2.) reflux, 1.5 h

2: 8.2 g / ammonia / CHCl₃ / 0.67 h

3: 70 percent / 0.33 h / 165 °C

4: 40 percent / m-chloroperbenzoic acid, NaHCO₃ / CHCl₃ / 3.5 h / Ambient temperature

With thionyl chloride; ammonia; sodium hydrogencarbonate; 3-chloro-benzenecarboperoxoic acid; In chloroform;
DOI:10.1021/ja00384a028

Reference yield:

: 21286-54-4
(+)-(1S)-Campher-10-sulfonsaeure-chlorid

: 81369-89-3
(R,R)-(+)-2-(d-10-camphorsulfonyl)-3-(2-chloro-5-nitrophenyl)oxaziridine

Guidance literature:: Multi-step reaction with 3 steps

1: 8.2 g / ammonia / CHCl₃ / 0.67 h

2: 70 percent / 0.33 h / 165 °C

3: 40 percent / m-chloroperbenzoic acid, NaHCO₃ / CHCl₃ / 3.5 h / Ambient temperature

With ammonia; sodium hydrogencarbonate; 3-chloro-benzenecarboperoxoic acid; In chloroform;
DOI:10.1021/ja00384a028