allyl (2,4,6-tri-O-acetyl-β-D-glucopyranosyl)-(1->3)-2,4-di-O-benzoyl-α-L-fucopyranoside

Base Information

Chemical Name:allyl (2,4,6-tri-O-acetyl-β-D-glucopyranosyl)-(1->3)-2,4-di-O-benzoyl-α-L-fucopyranoside
CAS No.:821794-41-6
Molecular Formula:C₃₅H₄₀O₁₅
Molecular Weight:700.694
Hs Code.:

Synonyms:allyl (2,4,6-tri-O-acetyl-β-D-glucopyranosyl)-(1->3)-2,4-di-O-benzoyl-α-L-fucopyranoside

Suppliers and Price of allyl (2,4,6-tri-O-acetyl-β-D-glucopyranosyl)-(1->3)-2,4-di-O-benzoyl-α-L-fucopyranoside

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of allyl (2,4,6-tri-O-acetyl-β-D-glucopyranosyl)-(1->3)-2,4-di-O-benzoyl-α-L-fucopyranoside

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of allyl (2,4,6-tri-O-acetyl-β-D-glucopyranosyl)-(1->3)-2,4-di-O-benzoyl-α-L-fucopyranoside

There total 2 articles about allyl (2,4,6-tri-O-acetyl-β-D-glucopyranosyl)-(1->3)-2,4-di-O-benzoyl-α-L-fucopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 27086-14-2
1,2,4,6-tetra-O-acetyl-β-D-glucopyranose

: 821794-41-6
allyl (2,4,6-tri-O-acetyl-β-D-glucopyranosyl)-(1->3)-2,4-di-O-benzoyl-α-L-fucopyranoside

Guidance literature:: Multi-step reaction with 4 steps

1.1: 100 percent / pyridine / CH₂Cl₂ / 0.5 h / -30 °C

2.1: hydrazine acetate / dimethylformamide / 1 h

2.2: 60 percent / 1,8-diazabicyclo[5.4.0]undec-7-ene / CH₂Cl₂ / 2 h / 0 °C

3.1: 60 percent / molecular sieves 4 Angstroem; TMSOTf / CH₂Cl₂ / 0.33 h / 20 °C

4.1: 93 percent / morpholine; tetrakis(triphenylphosphane)palladium / tetrahydrofuran / 2 h / 65 °C

With morpholine; pyridine; tetrakis(triphenylphosphine) palladium⁽⁰⁾; trimethylsilyl trifluoromethanesulfonate; 4 A molecular sieve; hydrazinium monoacetate; In tetrahydrofuran; dichloromethane; N,N-dimethyl-formamide;
DOI:10.1002/ejoc.200400255

Reference yield:

: 821794-38-1
1,2,4,6-tetra-O-acetyl-3-O-allyloxycarbonyl-β-D-glucopyranose

: 821794-41-6
allyl (2,4,6-tri-O-acetyl-β-D-glucopyranosyl)-(1->3)-2,4-di-O-benzoyl-α-L-fucopyranoside

Guidance literature:: Multi-step reaction with 3 steps

1.1: hydrazine acetate / dimethylformamide / 1 h

1.2: 60 percent / 1,8-diazabicyclo[5.4.0]undec-7-ene / CH₂Cl₂ / 2 h / 0 °C

2.1: 60 percent / molecular sieves 4 Angstroem; TMSOTf / CH₂Cl₂ / 0.33 h / 20 °C

3.1: 93 percent / morpholine; tetrakis(triphenylphosphane)palladium / tetrahydrofuran / 2 h / 65 °C

With morpholine; tetrakis(triphenylphosphine) palladium⁽⁰⁾; trimethylsilyl trifluoromethanesulfonate; 4 A molecular sieve; hydrazinium monoacetate; In tetrahydrofuran; dichloromethane; N,N-dimethyl-formamide;
DOI:10.1002/ejoc.200400255