{(PP₃)Rh(H)Cl}BPh₄

Base Information

Chemical Name:{(PP₃)Rh(H)Cl}BPh₄
CAS No.:115590-82-4
Molecular Formula:C₂₄H₂₀B*C₄₂H₄₃ClP₄Rh
Molecular Weight:1129.29
Hs Code.:

{(PP<sub>3</sub>)Rh(H)Cl}BPh<sub>4</sub>

Synonyms:{(PP₃)Rh(H)Cl}BPh₄

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Chemical Property of {(PP₃)Rh(H)Cl}BPh₄

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Technology Process of {(PP₃)Rh(H)Cl}BPh₄

There total 2 articles about {(PP₃)Rh(H)Cl}BPh₄ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

: 110827-50-4
{(PP₃)RhCl}

: 1493-13-6
trifluorormethanesulfonic acid

: 143-66-8
sodium tetraphenyl borate

: 115590-82-4
{(PP₃)Rh(H)Cl}BPh₄

Guidance literature:: In tetrahydrofuran; under N2- or Ar-atmosphere to a stirred suspension of {(PP3)RhCl} in THF HSO3CF3 was added; after formation of a pale lilac soln. solid NaBPh4 was added; pptn. by addn. of EtOH;; elem. anal.;;
DOI:10.1021/ja00227a022

Reference yield:

: 110827-50-4
{(PP₃)RhCl}

: 143-66-8
sodium tetraphenyl borate

: 65-85-0,8013-63-6
benzoic acid

: 115590-82-4
{cis-(hydride)(P(CH₂CH₂P(C₆H₅)2)3)RhCl}(BPh₄)

Guidance literature:: In tetrahydrofuran; ethanol; N2 or Ar atmosphere; gentle heating (40°C), addn. of NaBPh4 in EtOH; collecting, washing (EtOH and pentane), drying (N2-stream);
DOI:10.1021/om00118a040

Reference yield: 60.0%

: 115590-82-4
{(PP₃)Rh(H)Cl}BPh₄

: 109786-30-3
{(PP₃)RhH}

: 109786-35-8
{(PP3)Rh(η2-H2)}(1+)

Guidance literature:: With NaBH₄; In tetrahydrofuran; ethanol; byproducts: NaCl; under N2- or Ar-atmosphere to a boiling solution of {(PP3)Rh(H)Cl}BPh4 in THF, NaBH4 in hot ethanol was added portionwise; formation of {(PP3)RhH2}(1+) not found at the used reaction temp.; addn. of EtOH, concn.;; room temp.; formation of {(PP3)RhH2}(1+) depending on reaction temp.; separated crystals washed with ethanol, dest. water and ethanol; elem. anal.;;
DOI:10.1021/ja00227a022