beta-D-Glucopyranuronic acid, 1-(1,1'-biphenyl)-4-carboxylate

Base Information

• Chemical Name: beta-D-Glucopyranuronic acid, 1-(1,1'-biphenyl)-4-carboxylate
• CAS No.: 82206-03-9
• Molecular Formula: C₁₉H₁₈O₈
• Molecular Weight: 374.347
• Mol file: 82206-03-9.mol

Synonyms:beta-D-Glucopyranuronic acid, 1-(1,1’-biphenyl)-4-carboxylate

Chemical Property of beta-D-Glucopyranuronic acid, 1-(1,1'-biphenyl)-4-carboxylate

Chemical Property:

• Vapor Pressure: 4.86E-18mmHg at 25°C
• Boiling Point: 654.8°C at 760 mmHg
• Flash Point: 237.7°C
• Density: 1.53g/cm³

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of beta-D-Glucopyranuronic acid, 1-(1,1'-biphenyl)-4-carboxylate

There total 9 articles about beta-D-Glucopyranuronic acid, 1-(1,1'-biphenyl)-4-carboxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

methyl 1-O-(p-phenyl)benzoyl-β-D-glucopyranuronate → 1-O-(p-phenyl)benzoyl-β-D-glucopyranuronic acid (82206-03-9)

Guidance literature:

With Candida antarctica Type B lipase; sodium citrate; In water; dimethyl sulfoxide; at 40 ℃; for 9h; pH=5.0;

DOI:10.1021/jo701547b

Reference yield:

C26H26O11 (1105557-01-4) → 1-O-(p-phenyl)benzoyl-β-D-glucopyranuronic acid (82206-03-9)

Guidance literature:

Multi-step reaction with 4 steps

1: Aspergillus niger lipase AS Amano / dimethyl sulfoxide / 4 h / 40 °C / pH 5 / aq. buffer; Enzymatic reaction

2: dimethyl sulfoxide

3: Aspergillus niger lipase AS Amano / dimethyl sulfoxide / 4 h / 40 °C / pH 5 / aq. buffer; Enzymatic reaction

4: Candida antarctica Lipase type B / dimethyl sulfoxide / 1.5 h / pH 5 / aq. buffer; Enzymatic reaction

With Candida antarctica Lipase type B; Aspergillus niger lipase AS Amano; In dimethyl sulfoxide;

DOI:10.1016/j.molcatb.2010.12.014

Reference yield:

C26H26O11 (1105557-03-6) → 1-O-(p-phenyl)benzoyl-β-D-glucopyranuronic acid (82206-03-9)

Guidance literature:

Multi-step reaction with 2 steps

1: Aspergillus niger lipase AS Amano / dimethyl sulfoxide / 4 h / 40 °C / pH 5 / aq. buffer; Enzymatic reaction

2: Candida antarctica Lipase type B / dimethyl sulfoxide / 1.5 h / pH 5 / aq. buffer; Enzymatic reaction

With Candida antarctica Lipase type B; Aspergillus niger lipase AS Amano; In dimethyl sulfoxide;

DOI:10.1016/j.molcatb.2010.12.014

upstream raw materials:

C₂₆H₂₆O₁₁

C₂₆H₂₆O₁₁

methyl 1-O-(p-phenyl)benzoyl-2,4-di-O-acetyl-β-D-glucopyranuronate

3-phenylbenzoic acid